(2R,3R)-4-O-benzyl-2-ethylbutane-1,2,3,4-tetraol

Base Information

Chemical Name:(2R,3R)-4-O-benzyl-2-ethylbutane-1,2,3,4-tetraol
CAS No.:188925-45-3
Molecular Formula:C₁₃H₂₀O₄
Molecular Weight:240.299
Hs Code.:

Synonyms:

Suppliers and Price of (2R,3R)-4-O-benzyl-2-ethylbutane-1,2,3,4-tetraol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2R,3R)-4-O-benzyl-2-ethylbutane-1,2,3,4-tetraol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2R,3R)-4-O-benzyl-2-ethylbutane-1,2,3,4-tetraol

There total 7 articles about (2R,3R)-4-O-benzyl-2-ethylbutane-1,2,3,4-tetraol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 188925-43-1
(2R,4R,5R)-4-Benzyloxymethyl-5-ethyl-2-methyl-[1,3]dioxan-5-ol

: 188925-45-3
(2R,3R)-4-O-benzyl-2-ethylbutane-1,2,3,4-tetraol

Guidance literature:: With toluene-4-sulfonic acid; ethane-1,2-dithiol; In chloroform; for 3h; Heating;
DOI:10.1016/S0957-4166(96)00540-X

Reference yield:

: 100-39-0
benzyl bromide

: 188925-45-3
(2R,3R)-4-O-benzyl-2-ethylbutane-1,2,3,4-tetraol

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) Bu₂SnO, molecular sieves 4A, 2.) nBu₄N⁺I^- / 1.) toluene, reflux, 18 h, 2.) toluene, 70 deg C, 18 h

2: 1.) DMSO, oxalyl chloride, 2.) Et₃N / 1.) CH₂Cl₂, -60 deg C, 15 min, 2.) CH₂Cl₂, from -60 deg C to RT, 4 h

3: diethyl ether / 1 h / -78 °C

4: 53 percent / p-toluenesulphonic acid, 1,2-ethanedithiol / CHCl₃ / 3 h / Heating

With oxalyl dichloride; 4 A molecular sieve; tetra-(n-butyl)ammonium iodide; di(n-butyl)tin oxide; toluene-4-sulfonic acid; ethane-1,2-dithiol; dimethyl sulfoxide; triethylamine; In diethyl ether; chloroform;
DOI:10.1016/S0957-4166(96)00540-X

Reference yield:

: 188925-10-2
(2R,4S,5R)-4-Benzyloxymethyl-2-methyl-[1,3]dioxan-5-ol

: 188925-45-3
(2R,3R)-4-O-benzyl-2-ethylbutane-1,2,3,4-tetraol

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) DMSO, oxalyl chloride, 2.) Et₃N / 1.) CH₂Cl₂, -60 deg C, 15 min, 2.) CH₂Cl₂, from -60 deg C to RT, 4 h

2: diethyl ether / 1 h / -78 °C

3: 53 percent / p-toluenesulphonic acid, 1,2-ethanedithiol / CHCl₃ / 3 h / Heating

With oxalyl dichloride; toluene-4-sulfonic acid; ethane-1,2-dithiol; dimethyl sulfoxide; triethylamine; In diethyl ether; chloroform;
DOI:10.1016/S0957-4166(96)00540-X