calcium DL-2,3-dihydroxypropanoate

Base Information

• Chemical Name: calcium DL-2,3-dihydroxypropanoate
• CAS No.: 98870-54-3
• Molecular Formula: 2C₃H₅O₄*Ca
• Molecular Weight: 250.219
• Mol file: 98870-54-3.mol

Synonyms:

Chemical Property of calcium DL-2,3-dihydroxypropanoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of calcium DL-2,3-dihydroxypropanoate

There total 1 articles about calcium DL-2,3-dihydroxypropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → calcium DL-2,3-dihydroxypropanoate (14028-62-7,14028-63-8,65644-56-6,84145-22-2,98870-54-3)

Guidance literature:

glycerol; With sodium hydroxide; Rh(trop2NH)(PPh₃)(OTf); water; cyclohexanone; at 25 ℃; for 16h; Inert atmosphere;

With calcium chloride; In water; chemoselective reaction;

DOI:10.1002/anie.200804757

Reference yield:

triethylammonium dihydrogen phosphate + 4,4'-dimethoxytrityl chloride (40615-36-9) + calcium DL-2,3-dihydroxypropanoate (14028-62-7,14028-63-8,65644-56-6,84145-22-2,98870-54-3) → C24H24O6*C6H15N

Guidance literature:

4,4'-dimethoxytrityl chloride; calcium DL-2,3-dihydroxypropanoate; With pyridine; at 45 ℃; for 22h;

triethylammonium dihydrogen phosphate; In dichloromethane; pH=7 - 8;

Reference yield:

4,4'-dimethoxytrityl chloride (40615-36-9) + calcium DL-2,3-dihydroxypropanoate (14028-62-7,14028-63-8,65644-56-6,84145-22-2,98870-54-3) → C24H24O6*C6H15N

Guidance literature:

4,4'-dimethoxytrityl chloride; calcium DL-2,3-dihydroxypropanoate; With pyridine; at 45 ℃; for 22h;

triethylamine phosphate; In dichloromethane; water;

upstream raw materials:

glycerol

Refernces

• 1、 Berens, Ulrich,Scharf, Hans-Dieter. "The First Stereoselective Synthesis of Racemic β-Multistriatin: A Pheromone Component of the European Elm Bark Beetle Scolytus multistriatus (Marsh.)". . p. 5127 - 5134. Retrieved 2007/10/02.