[Ti{MePhSi(η⁵-C₅Me₄)₂}Cl₂]

Base Information

Chemical Name:[Ti{MePhSi(η⁵-C₅Me₄)₂}Cl₂]
CAS No.:1227490-67-6
Molecular Formula:C₂₅H₃₂Cl₂SiTi
Molecular Weight:479.401
Hs Code.:

[Ti{MePhSi(η<sup>5</sup>-C<sub>5</sub>Me<sub>4</sub>)<sub>2</sub>}Cl<sub>2</sub>]

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Chemical Property of [Ti{MePhSi(η⁵-C₅Me₄)₂}Cl₂]

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Technology Process of [Ti{MePhSi(η⁵-C₅Me₄)₂}Cl₂]

There total 1 articles about [Ti{MePhSi(η⁵-C₅Me₄)₂}Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 31168-87-3,18039-90-2
titanium trichloride tris(tetrahydrofuran)

: 1227490-66-5
(methyl)(phenyl)bis(2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)silane

: 1227490-67-6
[Ti{MePhSi(η⁵-C₅Me₄)₂}Cl₂]

Guidance literature:: With n-BuLi; aq. HCl; In tetrahydrofuran; byproducts: LiCl; Schlenk technique, N2, n-BuLi (22.2 mmol) added dropwise to soln. of SiMePh(C5(CH3)4)2 (11.1 mmol) at -50°C, stirred for 4 h at room temp., TiCl3(THF)3 (11.1 mmol) added, refluxed for 33 h; soln. concd., aq. HCl added at room temp., solid septd., washed with MeOH, crystd. from CH2Cl2 soln. over layered by MeOH, crystals isolated, washed with CHCl3/MeOH (1:5, v/v), MeOH, dried in air; elem. anal.;
DOI:10.1016/j.jorganchem.2010.01.037

Reference yield: 84.0%

: 1227490-67-6
[Ti{MePhSi(η⁵-C₅Me₄)₂}Cl₂]

: 7550-45-0
titanium tetrachloride

: 1227490-69-8
[(titanium(trichloride)(η5-C5(CH3)H4))2Si(methyl)(phenyl)]

Guidance literature:: In not given; Schlenk techniques, under N2; excess of TiCl4 (9 mmol) added to Ti complex (0.25 mmol), mixt. heated to 135°C with stirring for 21 h, cooled to room temp.; volatiles removed in vac., residue extracted with CH2Cl2, concd., soln. layered with hexane, crystd for 4 d, ppt. filtered off, filtrate concd.,stored in freezer (-28°C) for several d, crystals washed with he xane, dried in vac.; elem. anal.;
DOI:10.1016/j.jorganchem.2010.01.037