(S)-(-)-methyl p-tolyl sulfoxide

Base Information

Chemical Name:(S)-(-)-methyl p-tolyl sulfoxide
CAS No.:39066-80-3
Molecular Formula:C₈H₁₀OS
Molecular Weight:154.233
Hs Code.:

Synonyms:

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Chemical Property of (S)-(-)-methyl p-tolyl sulfoxide

Chemical Property:

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Technology Process of (S)-(-)-methyl p-tolyl sulfoxide

There total 2 articles about (S)-(-)-methyl p-tolyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 623-13-2
4-methylphenyl methylsulfide

: 1519-39-7
(R)-(+)-methyl p-tolyl sulfoxide

: 934-72-5,1519-39-7,5056-07-5,39066-80-3,90366-19-1
(S)-(-)-methyl p-tolyl sulfoxide

Guidance literature:: With dihydrogen peroxide; In water; at 20 ℃; for 24h;

Reference yield:

: 1517-82-4
(-)-(S)-O-menthyl p-toluenesulfinate

: 1519-39-7
(R)-(+)-methyl p-tolyl sulfoxide

: 934-72-5,1519-39-7,5056-07-5,39066-80-3,90366-19-1
(S)-(-)-methyl p-tolyl sulfoxide

Guidance literature:: In benzene; for 0.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;
DOI:10.1021/jo00138a026

Reference yield: 97.0%

: ammonium hexafluorophosphate

: cis-bis-(2,2′-bipyridine) dichlororuthenium(II) dihydrate

: 934-72-5,1519-39-7,5056-07-5,39066-80-3,90366-19-1
(S)-(-)-methyl p-tolyl sulfoxide

: cis-[Ru(2,2'-bipyridine)2(methyl p-tolyl sulfoxide)(Cl)]hexafluorophosphate

Guidance literature:: In water; ethylene glycol; other Radiation; a suspn. of the complex and CH3C6H4S(O)CH3 (2 equiv.) in (CH2OH)2 was heated for 2 min in a microwave oven (375 W), after cooling a sat. aq. soln. of NH4PF6 was added; diastereomeric excess is 73.9%; the ppt. was filtered, washed with H2O and (CH3CH2)2O and dried overnight; monitored by HPLC using a chiral column; separation of (S)-sulfoxideisomer;
DOI:10.1021/om000255l