bis(tetraethylammonium) cerium(IV) hexachloride

Base Information

• Chemical Name: bis(tetraethylammonium) cerium(IV) hexachloride
• CAS No.: 17116-10-8
• Molecular Formula: 2C₈H₂₀N*CeCl₆
• Molecular Weight: 613.345
• Mol file: 17116-10-8.mol

Synonyms:

Chemical Property of bis(tetraethylammonium) cerium(IV) hexachloride

Chemical Property:

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(tetraethylammonium) cerium(IV) hexachloride

There total 4 articles about bis(tetraethylammonium) cerium(IV) hexachloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

hydrated cerium(IV) sulfate + tetraethylammonium chloride (56-34-8) → bis(tetraethylammonium) cerium(IV) hexachloride (17116-10-8)

Guidance literature:

With hydrogenchloride; In water; at 5 ℃;

DOI:10.1021/ja510067v

Reference yield:

cerium(III) chloride heptahydrate + tetraethylammonium chloride (56-34-8) + tetrabutyl-ammonium chloride (1112-67-0) → tetraethylammonium hexachlorocerate(IV) (17116-10-8)

Guidance literature:

With thionyl chloride; In thionyl chloride; absence of moisture; refluxing of mixt. of Ce-complex with 2.4 equiv. ofBu4NCl (80 min), filtration, addn. of 2.1 equiv. of Et4NCl (pptn.); filtration, washing (petrolem ether with 5% SOCl2), drying (vac.); elem.anal.;

DOI:10.1016/S0020-1693(00)84726-X

Reference yield:

ammonium cerium (IV) nitrate (16774-21-3) + tetraethylammonium chloride (56-34-8) → tetraethylammonium hexachlorocerate(IV) (17116-10-8)

Guidance literature:

In hydrogenchloride; recrystd. from anhyd. acetonitrile or nitromethane;

upstream raw materials:

tetraethylammonium chloride

tetrabutyl-ammonium chloride

ammonium cerium (IV) nitrate