Silane, chlorodiphenyl[(1E)-2-phenylethenyl]-

Base Information

• Chemical Name: Silane, chlorodiphenyl[(1E)-2-phenylethenyl]-
• CAS No.: 117229-43-3
• Molecular Formula: C₂₀H₁₇ClSi
• Molecular Weight: 320.893
• Mol file: 117229-43-3.mol

Synonyms:

Chemical Property of Silane, chlorodiphenyl[(1E)-2-phenylethenyl]-

Chemical Property:

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Silane, chlorodiphenyl[(1E)-2-phenylethenyl]-

There total 1 articles about Silane, chlorodiphenyl[(1E)-2-phenylethenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + vinyldiphenylchlorosilane (18419-53-9) → trans-Ph2SiClCH=CHPh (117229-43-3)

Guidance literature:

[Cl₂(PCy₃)(IMesH₂)Ru(=CHPh)]; In dichloromethane; for 1h; Heating;

DOI:10.1016/j.jorganchem.2005.07.091

Reference yield: 71.0%

trans-Ph2SiClCH=CHPh (117229-43-3) + [dicarbonyl(η5-cyclopentadienyl)iron]trimethylsilane + lithium diisopropyl amide (4111-54-0) → {(η5-C5H4SiMe3)Fe(CO)2SiPh2-trans-CH=CHPh}

Guidance literature:

In tetrahydrofuran; (N2); addn. of LDA to a soln. of (η5-C5H5)Fe(CO)2SiMe3 in THF at 0°C; during stirring of the reaction mixt. for 40 min addn. of trans-(Cl)SiPh2CH=CHPh; permitting the soln. to warm to room temp. and addnl. stirring for 30 min;; solvent removal; extn. (CH2Cl2/hexane 40:60); column chromy. (silica gel, CH2Cl2/hexane 20:80 resp.) of the obtained crude material; recrystn. from hexane; elem. anal.;;

Reference yield: 35.0%

trans-Ph2SiClCH=CHPh (117229-43-3) + sodium dicarbonyl(cyclopentadienyl)ferrate → trans-{(η5-C5H5)Fe(CO)2SiPh2CH=CHPh}

Guidance literature:

In tetrahydrofuran; (N2); stirring of the mixt. for 30 min;; solvent removal; extn. (CH2Cl2/hexane 40:60); column chromy. (silica gel, CH2Cl2/hexane 20:80 resp.) of the obtained crude material; recrystn. from hexane; elem. anal.;;

upstream raw materials:

styrene

vinyldiphenylchlorosilane