{Ph₄P}2{Ni₃(edt)4}

Base Information

Chemical Name:{Ph₄P}2{Ni₃(edt)4}
CAS No.:106317-25-3
Molecular Formula:C₈H₁₆Ni₃S₈*2C₂₄H₂₀P
Molecular Weight:1223.61
Hs Code.:

{Ph<sub>4</sub>P}2{Ni<sub>3</sub>(edt)4}

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Chemical Property of {Ph₄P}2{Ni₃(edt)4}

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Technology Process of {Ph₄P}2{Ni₃(edt)4}

There total 3 articles about {Ph₄P}2{Ni₃(edt)4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 2751-90-8
tetraphenylphosphonium bromide

: 540-63-6
ethane-1,2-dithiol

: 83864-14-6
nickel dichloride

: 106317-25-3
{Ph₄P}2{Ni₃(edt)4}

Guidance literature:: With Na; In methanol; under pure nitrogen, solvents were degassed Addn. of a suspn. of NiCl2 to a soln. of Na and H2edt in MeOH, stirring for 2h, filtering onto Ph4PBr, during storage at -30°C for 2 days cystals separated; recrystn. from DMF/MeOH elem. anal.;

Reference yield: 12.0%

: nickel (II) chloride hexahydrate

: 2751-90-8
tetraphenylphosphonium bromide

: 540-63-6
ethane-1,2-dithiol

: 106317-25-3
{Ph₄P}2{Ni₃(edt)4}

: (PPh₄)2(Ni₂(SCH₂CH₂S)3)

Guidance literature:: With sodium metal; In ethanol; byproducts: NaCl; Na in EtOH and ethane-1,2-dithiol added followed by NiCl2, after 0.5 h ppt. filtrated and PPh4Br added to filtrate, mixt. storage for 36 h at room temp. and filtered; filtrate exposed to air for 24 h, mixt. filtered, extracted with hot EtOH or hot MeCN; crystals obtained upon continue storage at room temp.(EtOH) or in freezer at -20°C (MeCN); elem.anal.;
DOI:10.1016/S0277-5387(00)80927-4