Zn⁽²⁺⁾*2ReO₄^(1-)*2C₄H₈O=Zn(ReO₄)2(C₄H₈O)2

Base Information

• Chemical Name: Zn⁽²⁺⁾*2ReO₄^(1-)*2C₄H₈O=Zn(ReO₄)2(C₄H₈O)2
• CAS No.: 125934-15-8
• Molecular Formula: 2C₄H₈O*2O₄Re*Zn
• Molecular Weight: 710.013
• Mol file: 125934-15-8.mol

Synonyms:

Chemical Property of Zn⁽²⁺⁾*2ReO₄^(1-)*2C₄H₈O=Zn(ReO₄)2(C₄H₈O)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Zn⁽²⁺⁾*2ReO₄^(1-)*2C₄H₈O=Zn(ReO₄)2(C₄H₈O)2

There total 4 articles about Zn⁽²⁺⁾*2ReO₄^(1-)*2C₄H₈O=Zn(ReO₄)2(C₄H₈O)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

chloro{2,6-dimethyl-4-(trimethylsiloxy)phenyl}(tetrahydrofuran)zinc (138667-89-7) + rhenium(VII) oxide → Zn(2+)*2ReO4(1-)*2C4H8O=Zn(ReO4)2(C4H8O)2 (125934-15-8) + {2,6-dimethyl-4-(trimethylsiloxy)phenyl}trioxorhenium(VII) (138667-90-0)

Guidance literature:

In tetrahydrofuran; under N2, (Me3SiOXy)ZnCl(THF) added dropwise to Re2O7 (-78°C), warmed (room temp., 2 h), yellow soln., white pptn., stirred for 1 h; solvent removed in vac., extraction (pentane), concentration, cooled (-78°C), recrystn. (pentane); elem. anal.;

Reference yield: 36.0%

diphenylzinc (1078-58-6) + rhenium(VII) oxide → Zn(2+)*2ReO4(1-)*2C4H8O=Zn(ReO4)2(C4H8O)2 (125934-15-8) + phenyltrioxo(tetrahydrofuran)rhenium(VII) (138693-72-8)

Guidance literature:

In tetrahydrofuran; under N2, Ph2Zn added dropwise to Re2O7 (-78°C), warmed (room temp., 2 h), yellow soln., white pptn., stirred (1 h); solvent removed in vac., extraction (pentane), filtered, concentration, cooled (2 h, -78°C), filtered, dried in vac.; elem. anal.;

Reference yield: 28.0%

Quinuclidine (100-76-5) + bis(pentafluorophenyl)zinc (1799-90-2) + rhenium(VII) oxide + zinc(II) chloride (7646-85-7,24359-56-6) → Zn(2+)*2ReO4(1-)*2C4H8O=Zn(ReO4)2(C4H8O)2 (125934-15-8) + (pentafluorophenyl)trioxo(quinuclidine)rhenium(VII) (138667-88-6)

Guidance literature:

In tetrahydrofuran; diethyl ether; under N2, (C6F5)2Zn and ZnCl2 added dropwise to Re2O7 (-78°C), warmed (room temp., 2 h), white pptn., THF removed in vac., extraction (pentane), quinuclidine added, color changed to yellow; filtered, cooled (-30°C);

upstream raw materials:

bis(2,4,6-trimethylphenyl)-zinc

Quinuclidine

bis(pentafluorophenyl)zinc

zinc(II) chloride