C₂₃H₂₈O₃Si

Base Information

Chemical Name:C₂₃H₂₈O₃Si
CAS No.:1345024-14-7
Molecular Formula:C₂₃H₂₈O₃Si
Molecular Weight:380.559
Hs Code.:

C<sub>23</sub>H<sub>28</sub>O<sub>3</sub>Si

Synonyms:

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Chemical Property of C₂₃H₂₈O₃Si

Chemical Property:

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Technology Process of C₂₃H₂₈O₃Si

There total 10 articles about C₂₃H₂₈O₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1345024-08-9
((1R,4R,5R)-4-(((tert-butyldiphenylsilyl)oxy)methyl)-2-oxabicyclo[3.1.0]hexan-1-yl)methanol

: 1345024-14-7
C₂₃H₂₈O₃Si

Guidance literature:: ((1R,4R,5R)-4-(((tert-butyldiphenylsilyl)oxy)methyl)-2-oxabicyclo[3.1.0]hexan-1-yl)methanol; With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -78 ℃; for 1h; Inert atmosphere;

With triethylamine; In dichloromethane; at -78 - 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/jo201716c

Reference yield:

: 287933-72-6
tert-Butyl-[(R)-1-(2,3-dihydro-furan-3-yl)methoxy]-diphenyl-silane

: 1345024-14-7
C₂₃H₂₈O₃Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / Inert atmosphere

2.1: pyridine / dichloromethane / Inert atmosphere

3.1: boron trifluoride diethyl etherate / acetonitrile / 0.5 h / 0 - 20 °C / Inert atmosphere

4.1: methanol; sodium hydride / mineral oil / 0.25 h / 0 °C / Inert atmosphere

4.2: 0 °C / Inert atmosphere

5.1: triethylamine / dichloromethane / 0.5 h / 0 - 20 °C / Inert atmosphere

6.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 20 °C / Inert atmosphere

7.1: sodium hydride / mineral oil / 0 - 20 °C / Inert atmosphere

7.2: 20 °C / Inert atmosphere

8.1: diisobutylaluminium hydride / toluene / 0.5 h / -78 - 20 °C / Inert atmosphere

8.2: 20 °C / Inert atmosphere

9.1: diethylzinc / dichloromethane; toluene / 1 h / 0 - 20 °C / Inert atmosphere

10.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C / Inert atmosphere

10.2: 1 h / -78 - 20 °C / Inert atmosphere

With pyridine; methanol; osmium(VIII) oxide; oxalyl dichloride; boron trifluoride diethyl etherate; diethylzinc; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; 4-methylmorpholine N-oxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In dichloromethane; acetone; toluene; acetonitrile; mineral oil; tert-butyl alcohol; 9.1: Simmons-Smith reaction / 10.1: Swern oxidation / 10.2: Swern oxidation;
DOI:10.1021/jo201716c

Reference yield:

: 1345023-89-3
(2S,3R,4R)-4-(((tert-butyldiphenylsilyl)oxy)methyl)-2-cyanotetrahydrofuran-3-yl acetate

: 1345024-14-7
C₂₃H₂₈O₃Si

Guidance literature:: Multi-step reaction with 5 steps

1.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 96 h / Inert atmosphere

2.1: sodium hydride / mineral oil / 0 - 20 °C / Inert atmosphere

2.2: 20 °C / Inert atmosphere

3.1: diisobutylaluminium hydride / toluene / 0.5 h / -78 - 20 °C / Inert atmosphere

3.2: 20 °C / Inert atmosphere

4.1: diethylzinc / dichloromethane; toluene / 1 h / 0 - 20 °C / Inert atmosphere

5.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C / Inert atmosphere

5.2: 1 h / -78 - 20 °C / Inert atmosphere

With oxalyl dichloride; diethylzinc; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; toluene; mineral oil; 4.1: Simmons-Smith reaction / 5.1: Swern oxidation / 5.2: Swern oxidation;
DOI:10.1021/jo201716c