(C₂H₅)4N⁽¹⁺⁾*Fe(H)(CO)2(P(OC₆H₅)3)2^(1-)=(C₂H₅)4N{Fe(H)(CO)2(P(OC₆H₅)3)2}

Base Information

Chemical Name:(C₂H₅)4N⁽¹⁺⁾*Fe(H)(CO)2(P(OC₆H₅)3)2^(1-)=(C₂H₅)4N{Fe(H)(CO)2(P(OC₆H₅)3)2}
CAS No.:143788-58-3
Molecular Formula:C₈H₂₀N*C₃₈H₃₁FeO₈P₂
Molecular Weight:863.707
Hs Code.:

(C<sub>2</sub>H<sub>5</sub>)4N<sup>(1+)</sup>*Fe(H)(CO)2(P(OC<sub>6</sub>H<sub>5</sub>)3)2<sup>(1-)</sup>=(C<sub>2</sub>H<sub>5</sub>)4N{Fe(H)(CO)2(P(OC<sub>6</sub>H<sub>5</sub>)3)2}

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Chemical Property of (C₂H₅)4N⁽¹⁺⁾*Fe(H)(CO)2(P(OC₆H₅)3)2^(1-)=(C₂H₅)4N{Fe(H)(CO)2(P(OC₆H₅)3)2}

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Technology Process of (C₂H₅)4N⁽¹⁺⁾*Fe(H)(CO)2(P(OC₆H₅)3)2^(1-)=(C₂H₅)4N{Fe(H)(CO)2(P(OC₆H₅)3)2}

There total 1 articles about (C₂H₅)4N⁽¹⁺⁾*Fe(H)(CO)2(P(OC₆H₅)3)2^(1-)=(C₂H₅)4N{Fe(H)(CO)2(P(OC₆H₅)3)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: tetraethylammonium hydroxide

: 72573-42-3
(CO)2(P(OC₆H₅)3)2FeH₂

: 143788-54-9,143788-58-3
(C₂H₅)4N⁽¹⁺⁾*HFe(CO)2(P(OC₆H₅)3)2^(1-)={(C₂H₅)4N}{HFe(CO)2(P(OC₆H₅)3)2}

Guidance literature:: In tetrahydrofuran; under Ar, addn. of a methanolic soln. of Et4NOH to a soln. of H2Fe(CO)2(P(OC6H5)3)2 in THF at room temp., stirring for 30 min; evapn. (vac.), ice bath, addn. of hexane/diethyl ether, crystn., removing supernatant, washing (H2O), drying (vac.); elem. anal.;
DOI:10.1021/om00046a012

Reference yield: 88.0%

: 143788-54-9,143788-58-3
(C₂H₅)4N⁽¹⁺⁾*HFe(CO)2(P(OC₆H₅)3)2^(1-)={(C₂H₅)4N}{HFe(CO)2(P(OC₆H₅)3)2}

: 882-33-7
diphenyldisulfane

: (C₂H₅)4N⁽¹⁺⁾*(C₆H₅S)Fe(CO)2(P(OC₆H₅)3)2^(1-)={(C₂H₅)4N}{(C₆H₅S)Fe(CO)2(P(OC₆H₅)3)2}

Guidance literature:: In tetrahydrofuran; byproducts: PhSH; under Ar, addn. of THF to Et4N(HFe(CO)2(P(OC6H5)3)2) and PhSSPh to give a yellow-orange soln., stirring for 30 min; concentrating the soln. (vac.), addn. of hexane, cooling to 0°C overnight, pptn., removing mother liquor, washing (hexane), drying;
DOI:10.1021/om00046a012

Reference yield: 82.0%

: 143788-58-3,143788-54-9
(C₂H₅)4N⁽¹⁺⁾*Fe(H)(CO)2(P(OC₆H₅)3)2^(1-)=(C₂H₅)4N{Fe(H)(CO)2(P(OC₆H₅)3)2}

: 103-19-5
di(p-tolyl) disulfide

: 72573-42-3
(CO)2(P(OC₆H₅)3)2FeH₂

: (C₂H₅)4N⁽¹⁺⁾*(CH₃C₆H₄S)Fe(CO)2(P(OC₆H₅)3)2^(1-)=(C₂H₅)4N{(CH₃C₆H₄S)Fe(CO)2(P(OC₆H₅)3)2}

Guidance literature:: In tetrahydrofuran; byproducts: CH3C6H4SH; Ar-atmosphere; addn. of sulfide to Fe-complex (equimolar amts., 0°C), stirring (1 h); concn. (vac.), layering with hexane/Et2O=4:1, crystn. (0°C, 24 h), decantation, washing (cold hexane);