Rh(SbPh3)3Br(η2-C(O)CH=C(Cl)CH2)

Base Information

Chemical Name:Rh(SbPh3)3Br(η2-C(O)CH=C(Cl)CH2)
CAS No.:375387-27-2
Molecular Formula:C₅₈H₄₈BrClORhSb₃
Molecular Weight:1344.53
Hs Code.:

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Chemical Property of Rh(SbPh3)3Br(η2-C(O)CH=C(Cl)CH2)

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Technology Process of Rh(SbPh3)3Br(η2-C(O)CH=C(Cl)CH2)

There total 1 articles about Rh(SbPh3)3Br(η2-C(O)CH=C(Cl)CH2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 39194-71-3
Rh(CO)Cl{Sb(C₆H₅)3}3

: 106-96-7
propargyl bromide

: 375387-27-2
Rh(SbPh3)3Br(η2-C(O)CH=C(Cl)CH2)

Guidance literature:: In dichloromethane; soln. of Rh-complex in CH2Cl2 was treated with ligand at room temp., stirred for 1 h under Ar; vol. was reduced, hexane was added, filtered, washed with hexane, dried in vacuo; elem. anal.;
DOI:10.1016/S0022-328X(01)00879-8

Reference yield: 97.0%

: 375387-27-2
Rh(SbPh3)3Br(η2-C(O)CH=C(Cl)CH2)

: 16836-95-6
silver(I) 4-methylbenzenesulfonate

: 375387-30-7
Rh(SbPh3)3(OTs)(η2-C(O)CH=CClCH2)

Guidance literature:: In dichloromethane; byproducts: AgBr; Ag-salt was added to soln. of Rh-complex in CH2Cl2, stirred at room temp. for 90 min under Ar; filtered, concd., hexane was added with stirring, evapd., dried in vacuo; elem. anal.;
DOI:10.1016/S0022-328X(01)00879-8

Reference yield: 95.0%

: 375387-27-2
Rh(SbPh3)3Br(η2-C(O)CH=C(Cl)CH2)

: 2923-28-6
silver trifluoromethanesulfonate

: 375387-29-4
Rh(SbPh3)3(OTf)(η2-C(O)CH=C(Cl)CH2)

Guidance literature:: In dichloromethane; byproducts: AgBr; AgOTf was added to soln. of Rh-complex in CH2Cl2, stirred at room temp. for 75 min under Ar; filtered, concd., hexane was added with stirring, evapd. to dryness, crystd. from CH2Cl2-hexane, dried in vacuo for 2 ds;
DOI:10.1016/S0022-328X(01)00879-8