Fe(CO)3(1,2-bis(dicyclohexylphosphino)ethane)

Base Information

Chemical Name:Fe(CO)3(1,2-bis(dicyclohexylphosphino)ethane)
CAS No.:137038-87-0
Molecular Formula:C₂₉H₄₈FeO₃P₂
Molecular Weight:562.493
Hs Code.:

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Chemical Property of Fe(CO)3(1,2-bis(dicyclohexylphosphino)ethane)

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Technology Process of Fe(CO)3(1,2-bis(dicyclohexylphosphino)ethane)

There total 2 articles about Fe(CO)3(1,2-bis(dicyclohexylphosphino)ethane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 209795-21-1
(η(6)-naphthalene)Fe(1,2-bis(dicyclohexylphosphino)ethane)

: 201230-82-2
carbon monoxide

: 137038-87-0
Fe(CO)3(1,2-bis(dicyclohexylphosphino)ethane)

Guidance literature:: In tetrahydrofuran; CO-atmosphere; 1 atm. CO, stirring (room temp., 42 h); solvent removal, extn. into hexane, filtration, evapn. (reduced pressure);
DOI:10.1016/S0022-328X(97)00770-5

Reference yield: 20.0%

: 38720-22-8,142435-17-4,142435-16-3,38333-35-6
(2-methyl-4-phenyl-1-oxabuta-1,3-diene)tricarbonyliron⁽⁰⁾

: 23743-26-2
1,2-bis-(dicyclohexylphosphino)ethane

: 137038-87-0
(1,2-bis(dicyclohexylphosphino)ethane)Fe(CO)3

Guidance literature:: In tetrahydrofuran; under N2; soln. of complex treated with a slight excess of ligand, stirred for 16 h at room temp.; filtered, solvent removed (vac.), oily residue dissolved in CH2Cl2, chromy. (alumina, CH2Cl2/hexanes 1:3), collected, evapd. (vac.), recrystn. by dissolving in CH2Cl2, layered with 10-fold vol. of hexanes, cooled to -20°C for 24 h;
DOI:10.1021/ja00027a023

Reference yield:

: 137038-87-0
(1,2-bis(dicyclohexylphosphino)ethane)Fe(CO)3

: 1493-13-6
trifluorormethanesulfonic acid

: 137039-05-5
{Fe(CO)3((C₆H₁₁)2P(CH₂)2P(C₆H₁₁)2)H}⁽¹⁺⁾*CF₃SO₃^(1-)={Fe(CO)3((C₆H₁₁)2P(CH₂)2P(C₆H₁₁)2)H}CF₃SO₃

Guidance literature:: In dichloromethane; under N2; addn. of CF3SO3H to a stirred soln. of complex; not isolated, monitored by IR and NMR;
DOI:10.1021/ja00027a023