Stannane, hydroxytris(2-methyl-2-phenylpropyl)-

Base Information

• Chemical Name: Stannane, hydroxytris(2-methyl-2-phenylpropyl)-
• CAS No.: 1178-81-0
• Molecular Formula: C30H40OSn
• Molecular Weight: 535.357
• Mol file: 1178-81-0.mol

Synonyms:

Chemical Property of Stannane, hydroxytris(2-methyl-2-phenylpropyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Stannane, hydroxytris(2-methyl-2-phenylpropyl)-

There total 1 articles about Stannane, hydroxytris(2-methyl-2-phenylpropyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

fenbutatin oxide (13356-08-6,12684-28-5) → tris(2-phenyl-2-methylpropyl)tin hydroxide (1178-81-0)

Guidance literature:

With water; In benzene-d6; equilibrium reaction;; not isolated, detected by H1-NMR-spectroscopy;;

DOI:10.1515/znb-1986-0911

Reference yield: 90.0%

ferrocenecarboxylic acid (1271-42-7) + tris(2-phenyl-2-methylpropyl)tin hydroxide (1178-81-0) → tris(2-methyl-2-phenylpropyl)tin ferrocenecarboxylate

Guidance literature:

In benzene; for 5h; Dean-Stark; Reflux;

DOI:10.1515/mgmc-2014-0027

Reference yield: 88.0%

tris(2-phenyl-2-methylpropyl)tin hydroxide (1178-81-0) → trineophyltin hydride (63353-12-8)

Guidance literature:

With borane-THF; In tetrahydrofuran; addn. of borane soln. to trineophyltin hydroxide soln. under nitrogen with magnetic stirring; refluxing, 1 h; evapn. under reduced pressure; addn. of diethyl ether and water; stirring, 10 min.; removal of aq. layer by pipette; washing ether layer with water; repeating twice; drying over magnesium sulfate; filtration; evapn. in vac.; crystn.; elem. anal.; by the method of Chopa et al., synthesis, 1983, 722;

upstream raw materials:

fenbutatin oxide

Downstream raw materials:

fenbutatin oxide

trineophyltin hydride

3,5-(t-Bu)2-4-OH-C₆H₂COOSn(CH₂C(CH₃)2Ph)3

4-[tris(2-methyl-2-phenylpropyl)stannyloxy]benzaldehyde