Trineophyltin hydride

Base Information

• Chemical Name: Trineophyltin hydride
• CAS No.: 63353-12-8
• Molecular Formula: C30H40Sn
• Molecular Weight: 519.358
• DSSTox Substance ID: DTXSID60274801
• Mol file: 63353-12-8.mol

Synonyms:TRINEOPHYLTIN HYDRIDE;63353-12-8;CID 6327208;CTK2A9431;DTXSID60274801

Chemical Property of Trineophyltin hydride

Chemical Property:

• Melting Point: 50-51°C
• PSA: 0.00000
• LogP: 8.14690
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 519.207379
• Heavy Atom Count: 31
• Complexity: 437

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C[Sn](CC(C)(C)C1=CC=CC=C1)CC(C)(C)C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Trineophyltin hydride

There total 2 articles about Trineophyltin hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

tris(2-phenyl-2-methylpropyl)tin hydroxide (1178-81-0) → trineophyltin hydride (63353-12-8)

Guidance literature:

With borane-THF; In tetrahydrofuran; addn. of borane soln. to trineophyltin hydroxide soln. under nitrogen with magnetic stirring; refluxing, 1 h; evapn. under reduced pressure; addn. of diethyl ether and water; stirring, 10 min.; removal of aq. layer by pipette; washing ether layer with water; repeating twice; drying over magnesium sulfate; filtration; evapn. in vac.; crystn.; elem. anal.; by the method of Chopa et al., synthesis, 1983, 722;

Reference yield:

lithium aluminium tetrahydride (16853-85-3) + tris(2-methyl-2-phenylpropyl)stannane chloride (1178-79-6) → trineophyltin hydride (63353-12-8)

Guidance literature:

In not given;

DOI:10.1021/om700693p

Reference yield: 99.0%

dimethyl acetylenedicarboxylate (762-42-5) + trineophyltin hydride (63353-12-8) → (E)-2-trineophyltin-maleic acid dimethyl ester (460984-06-9)

Guidance literature:

In toluene; Irradiation (UV/VIS); (N2); soln. of alkyne and hydride in dry toluene irradiated at room temp. during 1 h; solvent distd. off under reduced pressure;

DOI:10.1016/S0022-328X(02)01213-5

upstream raw materials:

tris(2-phenyl-2-methylpropyl)tin hydroxide

lithium aluminium tetrahydride

tris(2-methyl-2-phenylpropyl)stannane chloride

Downstream raw materials:

(Z)-3-trineophyltin-3-phenyl-2-propenol

tris(2-methyl-2-phenylpropyl)stannane bromide

methyl 3-(trineophylstannyl)propanoate

tris(2-methyl-2-phenylpropyl)stannane chloride