trans-{Mn(CO)4(PPh₃)2} trifluoromethanesulfonate

Base Information

• Chemical Name: trans-{Mn(CO)4(PPh₃)2} trifluoromethanesulfonate
• CAS No.: 111635-47-3
• Molecular Formula: CF₃O₃S*C₄₀H₃₀MnO₄P₂
• Molecular Weight: 840.632
• Mol file: 111635-47-3.mol

Synonyms:

Chemical Property of trans-{Mn(CO)4(PPh₃)2} trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of trans-{Mn(CO)4(PPh₃)2} trifluoromethanesulfonate

There total 2 articles about trans-{Mn(CO)4(PPh₃)2} trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

mer,trans-Mn(CO)3(PPh3)2CHO (110351-58-1) + methyl trifluoromethanesulfonate (333-27-7) → methoxymethyl mer,trans-Mn(CO)3(PPh3)2 + trans-{Mn(CO)4(PPh3)2} trifluoromethanesulfonate (111635-47-3)

Guidance literature:

In dichloromethane; (N2); added Mn-complex to a soln. of CH3SO3CF3 at -78°C with stirring; warmed slowly to room temp.; stirred overnight (14 h); evapd. in vacuo; triturated with benzene; filtered; concentrated; mixed with hexane; cooled to -5°C; dissolved in CH2Cl2; mixed with hexane; chilled at -20°C; pptd.;

DOI:10.1021/om00050a065

Reference yield: 78.0%

mer,trans-Mn(CO)3(PPh3)2CHO (110351-58-1) + mer,trans-{Mn(CO)3(PPh3)2CHOCH3}SO3CF3 → methoxymethyl mer,trans-Mn(CO)3(PPh3)2 + trans-{Mn(CO)4(PPh3)2} trifluoromethanesulfonate (111635-47-3)

Guidance literature:

In not given; in 1:1 molar ratio;

DOI:10.1021/om00155a037

upstream raw materials:

mer,trans-Mn(CO)3(PPh₃)2CHO

methyl trifluoromethanesulfonate