3,3''-((1E,1'E)-((2-methylpropane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2',4',5,6'-tetramethyl-[1,1'-biphenyl]-2-olate)aluminum chloride

Base Information

Chemical Name:3,3''-((1E,1'E)-((2-methylpropane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2',4',5,6'-tetramethyl-[1,1'-biphenyl]-2-olate)aluminum chloride
CAS No.:1448442-71-4
Molecular Formula:C₃₈H₄₂AlClN₂O₂
Molecular Weight:621.198
Hs Code.:

3,3''-((1E,1'E)-((2-methylpropane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2',4',5,6'-tetramethyl-[1,1'-biphenyl]-2-olate)aluminum chloride

Synonyms:

Suppliers and Price of 3,3''-((1E,1'E)-((2-methylpropane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2',4',5,6'-tetramethyl-[1,1'-biphenyl]-2-olate)aluminum chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3,3''-((1E,1'E)-((2-methylpropane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2',4',5,6'-tetramethyl-[1,1'-biphenyl]-2-olate)aluminum chloride

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,3''-((1E,1'E)-((2-methylpropane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2',4',5,6'-tetramethyl-[1,1'-biphenyl]-2-olate)aluminum chloride

There total 5 articles about 3,3''-((1E,1'E)-((2-methylpropane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2',4',5,6'-tetramethyl-[1,1'-biphenyl]-2-olate)aluminum chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 1448442-61-2
3,3''-((1E,1'E)-((2-methylpropane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2',4',5,6'-tetramethyl-[1,1'-biphenyl]-2-ol)

: 96-10-6
diethylaluminium chloride

: 1448442-71-4
3,3''-((1E,1'E)-((2-methylpropane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2',4',5,6'-tetramethyl-[1,1'-biphenyl]-2-olate)aluminum chloride

Guidance literature:: In hexane; dichloromethane; at 0 - 22 ℃; for 12h;
DOI:10.1021/ja405151n

Reference yield:

: 6627-55-0
2-bromo-p-cresol

: 1448442-71-4
3,3''-((1E,1'E)-((2-methylpropane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2',4',5,6'-tetramethyl-[1,1'-biphenyl]-2-olate)aluminum chloride

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium hydride / tetrahydrofuran / 0.17 h / 0 - 22 °C / Reflux

1.2: 12 h / Reflux

2.1: triethylamine; formaldehyd / tetrahydrofuran; diethyl ether; toluene / 12 h / 0 - 80 °C

3.1: air / methanol / 7 h / 65 °C

4.1: dichloromethane; hexane / 12 h / 0 - 22 °C

With formaldehyd; sodium hydride; triethylamine; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; toluene; 1.1: |Kumada Cross-Coupling;
DOI:10.1021/ja405151n

Reference yield:

: 2633-66-1
2-mesitylmagnesium bromide

: 1448442-71-4
3,3''-((1E,1'E)-((2-methylpropane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2',4',5,6'-tetramethyl-[1,1'-biphenyl]-2-olate)aluminum chloride

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium hydride / tetrahydrofuran / 0.17 h / 0 - 22 °C / Reflux

1.2: 12 h / Reflux

2.1: triethylamine; formaldehyd / tetrahydrofuran; diethyl ether; toluene / 12 h / 0 - 80 °C

3.1: air / methanol / 7 h / 65 °C

4.1: dichloromethane; hexane / 12 h / 0 - 22 °C

With formaldehyd; sodium hydride; triethylamine; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; toluene; 1.1: |Kumada Cross-Coupling;
DOI:10.1021/ja405151n