Pt(PEt3)(κ2-P,C-PEt2CHMe)(C6Cl5)

Base Information

• Chemical Name: Pt(PEt3)(κ2-P,C-PEt2CHMe)(C6Cl5)
• CAS No.: 1272323-80-4
• Molecular Formula: C₁₈H₂₉Cl₅P₂Pt
• Molecular Weight: 679.721
• Mol file: 1272323-80-4.mol

Synonyms:

Chemical Property of Pt(PEt3)(κ2-P,C-PEt2CHMe)(C6Cl5)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pt(PEt3)(κ2-P,C-PEt2CHMe)(C6Cl5)

There total 1 articles about Pt(PEt3)(κ2-P,C-PEt2CHMe)(C6Cl5) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

cis-dichlorobis(triethylphosphine)platinum(II) (13965-02-1,14177-93-6,15692-07-6) + hexachlorobenzene (118-74-1,67471-27-6) → Pt(PEt3)(κ2-P,C-PEt2CHMe)(C6Cl5) (1272323-80-4)

Guidance literature:

With C₄H₉Li; In tetrahydrofuran; hexane; under N2 atm.; suspn. of C6Cl6 in THf cooled to -30°C; BuLi (hexane) added dropwise into stirred C6Cl6 mixt. over 5 min; stirred for 20 min; added dropwise to stirred suspn. of Pt complex in THF cooled to -30°C; stirred for 20 min; cooled; filtered; volatiles removed (vac.); dissolved (CHCl3); washed (H2O); volatiles removed (vac.); solid washed (EtOH); filtered; dried (vac.); recrystd. (CH2Cl2/EtOH);

DOI:10.1021/om1010879

upstream raw materials:

cis-dichlorobis(triethylphosphine)platinum(II)

hexachlorobenzene