4,10,12-Tetradecatriene-1,8,8-tricarboxylic acid, 14-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-5-methyl-, trimethyl ester, (E,Z,E)-

Base Information

Chemical Name:4,10,12-Tetradecatriene-1,8,8-tricarboxylic acid, 14-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-5-methyl-, trimethyl ester, (E,Z,E)-
CAS No.:118427-88-6
Molecular Formula:C37H50O7Si
Molecular Weight:634.885
Hs Code.:
Mol file:118427-88-6.mol

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Chemical Property of 4,10,12-Tetradecatriene-1,8,8-tricarboxylic acid, 14-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-5-methyl-, trimethyl ester, (E,Z,E)-

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Technology Process of 4,10,12-Tetradecatriene-1,8,8-tricarboxylic acid, 14-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-5-methyl-, trimethyl ester, (E,Z,E)-

There total 20 articles about 4,10,12-Tetradecatriene-1,8,8-tricarboxylic acid, 14-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-5-methyl-, trimethyl ester, (E,Z,E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 117832-47-0
(5E)-methyl 6-methyl-8-hydroxy-5-octenoate

: 118427-88-6
(5E,11Z,13E)-15-(tert-Butyl-diphenyl-silanyloxy)-9,9-bis-methoxycarbonyl-6-methyl-pentadeca-5,11,13-trienoic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 776.5 mg / NEt₃ / CH₂Cl₂ / 1 h / 0 °C

2: 1) NaH, 2) KI / 1) DMF/THF, a) 0 deg C, 30 min, b) rt, 30 min, 2) THF, 95 deg C, 6 h

3: 1) NaH / 1) THF/DMF, a) 0 deg C, 15 min, b) rt, 15 min, 2) THF/DMF, rt, 8 h

With sodium hydride; triethylamine; potassium iodide; In dichloromethane;

Reference yield:

: 117832-48-1
(E)-8-Methanesulfonyloxy-6-methyl-oct-5-enoic acid methyl ester

: 118427-88-6
(5E,11Z,13E)-15-(tert-Butyl-diphenyl-silanyloxy)-9,9-bis-methoxycarbonyl-6-methyl-pentadeca-5,11,13-trienoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1) NaH, 2) KI / 1) DMF/THF, a) 0 deg C, 30 min, b) rt, 30 min, 2) THF, 95 deg C, 6 h

2: 1) NaH / 1) THF/DMF, a) 0 deg C, 15 min, b) rt, 15 min, 2) THF/DMF, rt, 8 h

With sodium hydride; potassium iodide;

Reference yield:

: 117832-49-2
(4E)-4-methyl-1,1,8-trimethoxycarbonyl-4-octene

: 118427-95-5
1-chloro-6-(t-butyldiphenylsilyloxy)hexa-2Z,4E-diene

: 118427-88-6
(5E,11Z,13E)-15-(tert-Butyl-diphenyl-silanyloxy)-9,9-bis-methoxycarbonyl-6-methyl-pentadeca-5,11,13-trienoic acid methyl ester

Guidance literature:: With sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide; 0 gradC to room temperature;
DOI:10.1016/S0040-4039(00)82006-7