Fluorobis[2,4,6-tri(propan-2-yl)phenyl]borane

Base Information

• Chemical Name: Fluorobis[2,4,6-tri(propan-2-yl)phenyl]borane
• CAS No.: 118513-79-4
• Molecular Formula: C30H46BF
• Molecular Weight: 436.505
• DSSTox Substance ID: DTXSID20566370
• Wikidata: Q82451956
• Mol file: 118513-79-4.mol

Synonyms:118513-79-4;Fluorobis[2,4,6-tri(propan-2-yl)phenyl]borane;DTXSID20566370

Chemical Property of Fluorobis[2,4,6-tri(propan-2-yl)phenyl]borane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 8
• Exact Mass: 436.3676598
• Heavy Atom Count: 32
• Complexity: 467

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(C1=C(C=C(C=C1C(C)C)C(C)C)C(C)C)(C2=C(C=C(C=C2C(C)C)C(C)C)C(C)C)F

Technology Process of Fluorobis[2,4,6-tri(propan-2-yl)phenyl]borane

There total 2 articles about Fluorobis[2,4,6-tri(propan-2-yl)phenyl]borane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

2,4,6-triisopropyl-1-bromobenzene (21524-34-5) + boron trifluoride diethyl etherate (109-63-7) → Bis(2,4,6-triisopropylphenyl)fluoroborane (118513-79-4)

Guidance literature:

2,4,6-triisopropyl-1-bromobenzene; With magnesium; In tetrahydrofuran; ethylene dibromide; for 3h; Reflux;

boron trifluoride diethyl etherate; In tetrahydrofuran; ethylene dibromide; at -78 ℃; Reflux;

DOI:10.1002/chem.202101687

Reference yield: 74.0%

trifluoroborane diethyl ether (109-63-7) + (2,4,6-triisopropylphenyl)magnesium bromide (108894-99-1) → Bis(2,4,6-triisopropylphenyl)fluoroborane (118513-79-4)

Guidance literature:

Reference yield: 95.0%

Bis(2,4,6-triisopropylphenyl)fluoroborane (118513-79-4) → bis(2,4,6-triisopropylphenyl)borane (124242-73-5)

Guidance literature:

Bis(2,4,6-triisopropylphenyl)fluoroborane; With potassium hydride; In tetrahydrofuran; at 0 - 22 ℃; for 12h; Inert atmosphere;

With methyl iodide; In tetrahydrofuran; at 0 - 22 ℃; for 2h; Inert atmosphere;

DOI:10.1002/anie.201901132

upstream raw materials:

trifluoroborane diethyl ether

(2,4,6-triisopropylphenyl)magnesium bromide

2,4,6-triisopropyl-1-bromobenzene

boron trifluoride diethyl etherate

Downstream raw materials:

Benzylbis(2,4,6-triisopropylphenyl)borane

Phenylbis(2,4,6-triisopropylphenyl)borane

{Li(Et₂O)2P(t-Bu)B(C₆H₂(CH(CH₃)3)2)}

bis(2,4,6-triisopropylphenyl)borane