2-<(2E,6E)-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-7-methyl-3-<(tert-butyldimethylsilyloxy)methyl>-2,6-nonadienyl>-2-<2-trimethylsilylfuran-4-yl>-1,3-dithian

Base Information

Chemical Name:2-<(2E,6E)-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-7-methyl-3-<(tert-butyldimethylsilyloxy)methyl>-2,6-nonadienyl>-2-<2-trimethylsilylfuran-4-yl>-1,3-dithian
CAS No.:160084-16-2
Molecular Formula:C₃₇H₆₄O₂S₂Si₂
Molecular Weight:661.217
Hs Code.:

2-<(2E,6E)-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-7-methyl-3-<(tert-butyldimethylsilyloxy)methyl>-2,6-nonadienyl>-2-<2-trimethylsilylfuran-4-yl>-1,3-dithian

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Chemical Property of 2-<(2E,6E)-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-7-methyl-3-<(tert-butyldimethylsilyloxy)methyl>-2,6-nonadienyl>-2-<2-trimethylsilylfuran-4-yl>-1,3-dithian

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Technology Process of 2-<(2E,6E)-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-7-methyl-3-<(tert-butyldimethylsilyloxy)methyl>-2,6-nonadienyl>-2-<2-trimethylsilylfuran-4-yl>-1,3-dithian

There total 16 articles about 2-<(2E,6E)-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-7-methyl-3-<(tert-butyldimethylsilyloxy)methyl>-2,6-nonadienyl>-2-<2-trimethylsilylfuran-4-yl>-1,3-dithian which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 160084-06-0
2-trimethylsilyl-4-(1,3-dithian-2-yl)-furan

: 160084-14-0
tert-Butyl-[(E)-2-[2-chloro-eth-(E)-ylidene]-6-methyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-oct-5-enyloxy]-dimethyl-silane

: 160084-16-2
2-<(2E,6E)-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-7-methyl-3-<(tert-butyldimethylsilyloxy)methyl>-2,6-nonadienyl>-2-<2-trimethylsilylfuran-4-yl>-1,3-dithian

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -80 ℃; for 12h; Yield given;
DOI:10.1016/S0040-4020(01)85353-9

Reference yield:

: 488-93-7
3-Furoic acid

: 160084-16-2
2-<(2E,6E)-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-7-methyl-3-<(tert-butyldimethylsilyloxy)methyl>-2,6-nonadienyl>-2-<2-trimethylsilylfuran-4-yl>-1,3-dithian

Guidance literature:: Multi-step reaction with 6 steps

1: 69 percent / pyridinium hydrobromide perbromide / acetic acid

2: BuLi / diethyl ether; various solvent(s) / 2.5 h / -60 - 25 °C

3: LiAlH₄ / tetrahydrofuran / 2 h / Ambient temperature

4: 79 percent / Swern oxidation

5: 84 percent / BF₃*Et₂O / CHCl₃ / 7 h / Ambient temperature

6: n-butyllithium / tetrahydrofuran; various solvent(s) / 12 h / -80 °C

With lithium aluminium tetrahydride; n-butyllithium; boron trifluoride diethyl etherate; pyridinium hydrobromide perbromide; In tetrahydrofuran; diethyl ether; chloroform; acetic acid;
DOI:10.1016/S0040-4020(01)85353-9

Reference yield:

: 58832-36-3
5-bromofuran-3-carboxylic acid

: 160084-16-2
2-<(2E,6E)-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-7-methyl-3-<(tert-butyldimethylsilyloxy)methyl>-2,6-nonadienyl>-2-<2-trimethylsilylfuran-4-yl>-1,3-dithian

Guidance literature:: Multi-step reaction with 5 steps

1: BuLi / diethyl ether; various solvent(s) / 2.5 h / -60 - 25 °C

2: LiAlH₄ / tetrahydrofuran / 2 h / Ambient temperature

3: 79 percent / Swern oxidation

4: 84 percent / BF₃*Et₂O / CHCl₃ / 7 h / Ambient temperature

5: n-butyllithium / tetrahydrofuran; various solvent(s) / 12 h / -80 °C

With lithium aluminium tetrahydride; n-butyllithium; boron trifluoride diethyl etherate; In tetrahydrofuran; diethyl ether; chloroform;
DOI:10.1016/S0040-4020(01)85353-9