9-Benzyl-3,6-dibroMocarbazole

Base Information

• Chemical Name: 9-Benzyl-3,6-dibroMocarbazole
• CAS No.: 118599-27-2
• Molecular Formula: C19H13Br2N
• Molecular Weight: 415.127
• DSSTox Substance ID: DTXSID00384337
• Nikkaji Number: J629.486C
• Wikidata: Q82176411
• Mol file: 118599-27-2.mol

Synonyms:9-benzyl-3,6-dibromocarbazole;

Chemical Property of 9-Benzyl-3,6-dibroMocarbazole

Chemical Property:

• Melting Point: 160.0 to 164.0 °C
• PSA: 4.93000
• LogP: 6.36780
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 6.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 414.93943
• Heavy Atom Count: 22
• Complexity: 356

Purity/Quality:

97% ^*data from raw suppliers

9-Benzyl-3,6-dibromocarbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)CN2C3=C(C=C(C=C3)Br)C4=C2C=CC(=C4)Br

Technology Process of 9-Benzyl-3,6-dibroMocarbazole

There total 10 articles about 9-Benzyl-3,6-dibroMocarbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

3,6-dibromo-9H-carbazole (6825-20-3) + benzyl bromide (100-39-0) → 9-benzyl-3,6-dibromo-9H-carbazole (118599-27-2)

Guidance literature:

3,6-dibromo-9H-carbazole; With sodium hydride; In N,N-dimethyl-formamide; at 20 ℃; for 1h; Inert atmosphere;

benzyl bromide; In N,N-dimethyl-formamide; at 20 ℃; for 12h; Inert atmosphere;

Reference yield: 98.0%

9-benzyl-9H-carbazole (19402-87-0) → 9-benzyl-3,6-dibromo-9H-carbazole (118599-27-2)

Guidance literature:

With bromine; In acetic acid; at 20 ℃; for 2h;

DOI:10.1002/chem.201303194

Reference yield: 97.0%

3,6-dibromo-9H-carbazole (6825-20-3) + benzyl alcohol (100-51-6,185532-71-2) → 9-benzyl-3,6-dibromo-9H-carbazole (118599-27-2)

Guidance literature:

With (trimethyl-λ5-phosphanyliden)acetonitrile; In toluene; at 110 ℃; for 15h;

DOI:10.1016/S0040-4039(02)00217-4

upstream raw materials:

9-benzyl-9H-carbazole

3,6-dibromo-9H-carbazole

benzyl chloride

3,6-dibromocarbazole nitranion

Downstream raw materials:

3,6-diethynyl-9-benzylcarbazole

9-benzyl-3,6-bis-triisopropylsilanyl-9H-carbazole

9-benzyl-3,6-di(9-carbazolyl)-9H-carbazole

N³,N³,N⁶,N⁶-tetrakis(4-methoxyphenyl)-9-H-carbazole-3,6-diamine