Re((2-phenylazo)pyridine)2(CO)2I₃

Base Information

• Chemical Name: Re((2-phenylazo)pyridine)2(CO)2I₃
• CAS No.: 1217532-78-9
• Molecular Formula: C₂₄H₁₈N₆O₂Re*I₃
• Molecular Weight: 989.366
• Mol file: 1217532-78-9.mol

Synonyms:

Chemical Property of Re((2-phenylazo)pyridine)2(CO)2I₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Re((2-phenylazo)pyridine)2(CO)2I₃

There total 1 articles about Re((2-phenylazo)pyridine)2(CO)2I₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

Re(C5H4NN2C6H5)2(CO)2 + iodine (7553-56-2,12190-71-5,8031-47-8) → Re((2-phenylazo)pyridine)2(CO)2I3 (1217532-78-9)

Guidance literature:

In dichloromethane; soln. of I2 in CH2Cl2 added dropwise to CH2Cl2 soln. of Re-complex; solvent evapd. by rotary evaporator, washed with hexane, crystd. by slowdiffusion of CH2Cl2 soln. into hexane; elem. anal.;

DOI:10.1021/ic9016195

Reference yield:

Re((2-phenylazo)pyridine)2(CO)2I3 (1217532-78-9) → Re(C5H4NN2C6H5)2(CO)2

Guidance literature:

With hydrazine; In water; acetonitrile; aq. soln. of N2H4 added to MeCN soln. of Re-complex;

DOI:10.1021/ic9016195

Reference yield:

Re((2-phenylazo)pyridine)2(CO)2I3 (1217532-78-9) → Re(C5H4NN2C6H5)2(CO)2(1-)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrazine / acetonitrile; water

2: cobaltocene / chloroform-d1

With hydrazine; cobaltocene; In chloroform-d1; water; acetonitrile;

DOI:10.1021/ic9016195

upstream raw materials:

iodine