Propanoic acid, 2-methyl-, 3,7-dimethyl-2,6-octadienyl ester

Base Information

• Chemical Name: Propanoic acid, 2-methyl-, 3,7-dimethyl-2,6-octadienyl ester
• CAS No.: 1188-06-3
• Molecular Formula: C₁₄H₂₄O₂
• Molecular Weight: 224.343
• Mol file: 1188-06-3.mol

Synonyms:

Chemical Property of Propanoic acid, 2-methyl-, 3,7-dimethyl-2,6-octadienyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Propanoic acid, 2-methyl-, 3,7-dimethyl-2,6-octadienyl ester

There total 4 articles about Propanoic acid, 2-methyl-, 3,7-dimethyl-2,6-octadienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 4.0%

Geraniol (106-24-1) + isobutyric Acid (79-31-2) → geranyl 2-methylpropanoate (1188-06-3,2345-24-6,2345-26-8)

Guidance literature:

In hexane; at 30 ℃; for 72h; Corynebacterium sp. S-401;

Reference yield:

Geraniol (106-24-1) + isobutyryl chloride (79-30-1) → geranyl 2-methylpropanoate (1188-06-3,2345-24-6,2345-26-8)

Guidance literature:

With pyridine; In methylene chloride (CH₂ Cl₂);

Reference yield:

Geraniol (106-24-1) + Ethyl isobutyrate (97-62-1) → geranyl 2-methylpropanoate (1188-06-3,2345-24-6,2345-26-8)

Guidance literature:

With recombinant acyltransferase from Mycobacterium smegmatis; In aq. phosphate buffer; at 25 ℃; for 48h; pH=8; Green chemistry; Enzymatic reaction;

DOI:10.1021/acs.jafc.9b01790

upstream raw materials:

Geraniol

isobutyric acetic anhydride

isobutyric Acid

isobutyryl chloride

Refernces

• 1、 -. "Tyrosinase inhibitors". . . Retrieved 2008/06/13.
• 2、 Iwai, Mieko,Okumura, Susumu,Tsujisaka, Yoshio. "Synthesis of Terpene Alcohol Esters by Lipase". . p. 2731 - 2732. Retrieved 2007/10/02.