tricarbonyl(η6-α-cyclohexyl-2-methoxybenzyl alcohole)chromium(0)

Base Information

• Chemical Name: tricarbonyl(η6-α-cyclohexyl-2-methoxybenzyl alcohole)chromium(0)
• CAS No.: 189020-42-6
• Molecular Formula: C₁₇H₂₀CrO₅
• Molecular Weight: 356.339
• Mol file: 189020-42-6.mol

Synonyms:

Chemical Property of tricarbonyl(η6-α-cyclohexyl-2-methoxybenzyl alcohole)chromium(0)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tricarbonyl(η6-α-cyclohexyl-2-methoxybenzyl alcohole)chromium(0)

There total 2 articles about tricarbonyl(η6-α-cyclohexyl-2-methoxybenzyl alcohole)chromium(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

(2R)-tricarbonyl[η-6-2-trimethylphenylsilylanisole]chromium(0) (69786-79-4,170079-61-5,156926-83-9) + benzaldehyde (100-52-7) → tricarbonyl(η6-α-cyclohexyl-2-methoxybenzyl alcohole)chromium(0) (189020-42-6,158880-83-2,189020-38-0)

Guidance literature:

With lithium chloride; In tetrahydrofuran; LiCl soln. addn. in 1 portion to chiral base at -78°C, stirring 5min, Cr-compd. dropping, aldehyde addn. (1 portion), keeping 30 min at -78°C, satd. aq. NH4Cl addn., warming, extn. (CH2Cl2), washing (H 2O), drying (MgSO4), solvent evapn.; residue flash column chromy. (40% Et2O/light petroleum);

Reference yield: 83.0%

(η6-anisol)tricarbonyl chromium (12116-44-8) → tricarbonyl(η6-α-cyclohexyl-2-methoxybenzyl alcohole)chromium(0) (189020-42-6,158880-83-2,189020-38-0)

Guidance literature:

With lithium chloride;

upstream raw materials:

(2R)-tricarbonyl[η-6-2-trimethylphenylsilylanisole]chromium(0)

benzaldehyde

(η6-anisol)tricarbonyl chromium