1,1'-(Ethenylphenylsilylene)bis[piperidine]

Base Information

Chemical Name:1,1'-(Ethenylphenylsilylene)bis[piperidine]
CAS No.:87439-36-9
Molecular Formula:C₁₈H₂₈N₂Si
Molecular Weight:300.519
Hs Code.:
DSSTox Substance ID:DTXSID001261554

Synonyms:1,1'-(Ethenylphenylsilylene)bis[piperidine];DTXSID001261554;87439-36-9

Suppliers and Price of 1,1'-(Ethenylphenylsilylene)bis[piperidine]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,1'-(Ethenylphenylsilylene)bis[piperidine]

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:300.202175436
Heavy Atom Count:21
Complexity:308

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C=C[Si](C1=CC=CC=C1)(N2CCCCC2)N3CCCCC3

Technology Process of 1,1'-(Ethenylphenylsilylene)bis[piperidine]

There total 2 articles about 1,1'-(Ethenylphenylsilylene)bis[piperidine] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 110-89-4
piperidine

: 7719-02-0
phenylvinyldichlorosilane

: 87439-36-9
Phenyldipiperidinovinylsilan

Guidance literature:: In diethyl ether; 1) 14 h at 20 deg C; 2) 2 h, reflux;
DOI:10.1002/jlac.198319830605

Reference yield:

: 108-90-7
chlorobenzene

: 87439-36-9
Phenyldipiperidinovinylsilan

Guidance literature:: Multi-step reaction with 2 steps

1: 1) Mg / 1) THF; 2) ether, first 12 h at 20 deg C then 3 h, reflux

2: 86 percent / diethyl ether / 1) 14 h at 20 deg C; 2) 2 h, reflux

With magnesium; In diethyl ether;
DOI:10.1002/jlac.198319830605

Reference yield:

: 87439-36-9
Phenyldipiperidinovinylsilan

: 104549-79-3
Sila-Cycrimin

Guidance literature:: Multi-step reaction with 4 steps

1: 1) 15 percent n-BuLi / 1) THF, hexane, 40 deg C, 40 min.; 2) THF, 2 h, 40 deg C; 12 h, 20 deg C

2: 80 percent / 20 h / Heating

3: 1) Mg, iodine / 1) ether, 20 min., reflux; 2) ether, first 16 h at 20 deg C, then 4 h, reflux

4: 77 percent / ethanol; H₂O / 20 h / 20 °C

With n-butyllithium; iodine; magnesium; In ethanol; water;
DOI:10.1002/jlac.198319830605