diphenylthallium(III) dithiophosphinate

Base Information

• Chemical Name: diphenylthallium(III) dithiophosphinate
• CAS No.: 166669-92-7
• Molecular Formula: C₂₄H₃₂PS₂Tl
• Molecular Weight: 620.007
• Mol file: 166669-92-7.mol

Synonyms:

Chemical Property of diphenylthallium(III) dithiophosphinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenylthallium(III) dithiophosphinate

There total 2 articles about diphenylthallium(III) dithiophosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

ammonium dicyclohexyldithiophosphinate (2512-57-4) + diphenyl (monobromo) thallium (10192-61-7) → diphenylthallium(III) dithiophosphinate (166669-92-7)

Guidance literature:

In chloroform; byproducts: NH4Br; dropwise addn. of 1 equiv. of phosphinate to Tl-compd., stirring (1 day); concn. (vac.), treatment with EtOH (pptn.), filtration, washing (EtOH),drying (vac.); elem. anal.;

DOI:10.1039/DT9950001403

Reference yield:

Dicyclohexyldithiophosphinic acid (2512-58-5) + diphenylthallium(III) hydroxide → diphenylthallium(III) dithiophosphinate (166669-92-7)

Guidance literature:

In chloroform-d1; byproducts: benzene; slight excess of phosphinic acid, shaking (several days, (1)H-NMR monitoring); slow evapn.;

DOI:10.1039/DT9950001403

upstream raw materials:

ammonium dicyclohexyldithiophosphinate

diphenyl (monobromo) thallium

Dicyclohexyldithiophosphinic acid