10192-61-7

Basic information

• Product Name: Thallium, bromodiphenyl-
• CAS NO: 10192-61-7
• Molecular Formula: C12H10BrTl
• Molecular Weight: 438.498
• Mol File: 10192-61-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Thallium, bromodiphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Thallium, bromodiphenyl-(10192-61-7)
• EPA Substance Registry System: Thallium, bromodiphenyl-(10192-61-7)

Safety Data

• Hazardous Substances Data: 10192-61-7(Hazardous Substances Data)

Upstream product

• 603-33-8 triphenylbismuthane 
• 1735-62-2 Bromo-bis-(pentafluorphenyl)-thallium(III) 
• 143-66-8 sodium tetraphenyl borate 
• 587-85-9 diphenylmercury(II) 
• 603-36-1 triphenylantimony 
• 98-80-6 phenylboronic acid 
• 10035-10-6 hydrogen bromide 
• 100-63-0 phenylhydrazine 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 7726-95-6 bromine 

Downstream Products

• 591-50-4 iodobenzene 
• 595-90-4 tetraphenyltin(IV) 
• 1666-13-3 diphenyl diselenide 
• 616900-08-4 diphenylthallium(III) ethylxanthate 
• 616900-09-5 diphenylthallium(III) isopropylxanthate 
• 616900-10-8 diphenylthallium(III) benzylxanthate 
• 3003-04-1 thallium(III) triphenyl 
• 622854-61-9 [Tl(C₆H₅)2(CH₃OC₆H₄CHNNC(S)NH₂)] 
• 622854-58-4 [Tl(C₆H₅)2(C₅H₈NNC(S)NH₂)] 
• 622854-62-0 [Tl(C₆H₅)2(C₆H₅C(CH₃)NNC(S)NH₂)] 
• 622854-59-5 [Tl(C₆H₅)2(C₆H₅CHNNC(S)NH₂)] 
• 622854-63-1 [Tl(C₆H₅)2(C₄H₃OCHNNC(S)NH₂)] 
• 169624-74-2 [Tl(C₆H₅)2((C₆H₅)2PSNPS(C₆H₅)2)] 
• 616900-07-3 diphenylthallium(III) methylxanthate 

Relevant articles and documents

Thallium(III) complexes of the metalloligands [Pt2(μ-S)2(PPh3)4] and [Pt2(μ-Se)2(PPh3)4]

Reactions of [Pt2(μ-S)2(PPh3)4] with the diarylthallium(III) bromides Ar2TlBr [Ar = Ph and p-ClC6H4] in methanol gave good yields of the thallium(III) adducts [Pt2(μ-S)2(PPh3)4TlAr2]+, isolated as their BPh4- salts. The corresponding selenide complex [Pt2(μ-Se)2(PPh3)4TlPh2]BPh4 was similarly synthesised from [Pt2(μ-Se)2(PPh3)4], Ph2TlBr and NaBPh4. The reaction of [Pt2(μ-S)2(PPh3)4] with PhTlBr2 gave [Pt2(μ-S)2(PPh3)4TlBrPh]+, while reaction with TlBr3 gave the dibromothallium(III) adduct [Pt2(μ-S)2(PPh3)4TlBr2]+[TlBr4]-. The latter complex is a rare example of a thallium(III) dihalide complex stabilised solely by sulfur donor ligands. X-ray crystal structure determinations on the complexes [Pt2(μ-S)2(PPh3)4TlPh2]BPh4, [Pt2(μ-S)2(PPh3)4TlBrPh]BPh4 and [Pt2(μ-S)2(PPh3)4TlBr2][TlBr4] reveal a greater interaction between the thallium(III) centre and the two sulfide ligands on stepwise replacement of Ph by Br, as indicated by shorter Tl-S and Pt?Tl distances, and an increasing S-Tl-S bond angle. Investigations of the ESI MS fragmentation behaviour of the thallium(III) complexes are reported.

Synthesis of Diphenylthallium Acetate and Bromide from Phenylhydrazine and Thallium(III) Oxide

A new procedure for synthesis of diphenylthallium acetate and bromide was developed, involving reaction of phenylhydrazine with thallium(III) oxide to give organothallium compounds. Certain factors affecting this reaction were studied.