[platinum(II)(p-SC₆F₄(CF₃))2(dppe)]

Base Information

• Chemical Name: [platinum(II)(p-SC₆F₄(CF₃))2(dppe)]
• CAS No.: 954379-91-0
• Molecular Formula: C₄₀H₂₄F₁₄P₂PtS₂
• Molecular Weight: 1091.77

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Chemical Property of [platinum(II)(p-SC₆F₄(CF₃))2(dppe)]

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Technology Process of [platinum(II)(p-SC₆F₄(CF₃))2(dppe)]

There total 1 articles about [platinum(II)(p-SC₆F₄(CF₃))2(dppe)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.7%

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7) + Pb(p-SC6F4(CF3))2 → [platinum(II)(p-SC6F4(CF3))2(dppe)] (954379-91-0)

Guidance literature:

In acetone; byproducts: PbCl2; under N2, 1 equiv. of Pb-salt in acetone was added to the P-comp. in acetone, stirring at room temp. for 24 h; PbCl2 was filtered off via silica gel, soln. was evapd., recrystn. from acetone, elem. anal.;

DOI:10.1016/j.poly.2007.05.025

Reference yield:

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7) + [platinum(II)(p-SC6F4(CF3))2(dppe)] (954379-91-0) + silver trifluoromethanesulfonate (2923-28-6) → [Pt(μ-p-SC6F4CF3)(dppe)]2(SO3CF3)2

Guidance literature:

In acetone; byproducts: AgCl; 2 equiv. of Ag-salt in acetoine was added to PtCl2-complex in acetone, stirring for 24 h at room temp., soln. was filtered through Celite, 1 equiv. of F-compd. in acetone was added, stirring for 7 h; slow evapn., recrystn. from acetone by hexane diffusion, elem. anal.;

DOI:10.1016/j.poly.2007.05.025

Reference yield:

(1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II) (19978-61-1) + [platinum(II)(p-SC6F4(CF3))2(dppe)] (954379-91-0) + silver trifluoromethanesulfonate (2923-28-6) → [(dppe)palladium(II)(μ-p-SC6F4(CF3))2(platinum(II))(dppe)](OTf)2

Guidance literature:

In acetone; byproducts: [Pt2(dppe)2(SC6F4(CF3))2](OTf)2, [Pd2(dppe)2(SC6F4(CF3))2](OTf)2; Schlenk tube technique, under N2; AgSO3CF3 (0.139 mmol) added to soln. of PtCl2(dppe) (0.070 mmol), stirred for 24 h, filtered, stoich. amount of Pt(p-SC6F4CF3)2(dppe) added, shaken for 12 h; mixt. of three complexes;

DOI:10.1016/j.ica.2009.07.036

upstream raw materials:

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

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