benzil α-monoxime benzoylhydrazone

Base Information

• Chemical Name: benzil α-monoxime benzoylhydrazone
• CAS No.: 22051-51-0
• Molecular Formula: C₂₁H₁₇N₃O₂
• Molecular Weight: 343.385
• Mol file: 22051-51-0.mol

Synonyms:

Chemical Property of benzil α-monoxime benzoylhydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzil α-monoxime benzoylhydrazone

There total 2 articles about benzil α-monoxime benzoylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzilmonoxime (574-15-2,574-16-3,14090-77-8,5351-34-8) + benzoic acid hydrazide (613-94-5) → benzil α-monoxime benzoylhydrazone (22051-51-0)

Guidance literature:

With hydrogenchloride; In ethanol;

DOI:10.1039/j39690001034

Reference yield:

(Z)-benzilmonooxime (574-16-3,5351-34-8) → benzil α-monoxime benzoylhydrazone (22051-51-0)

Guidance literature:

Multi-step reaction with 2 steps

1: alcohol; hydrazine hydrate

2: alcohol

With ethanol; hydrazine hydrate;

Reference yield: 65.0%

benzil α-monoxime benzoylhydrazone (22051-51-0) + manganese(III) triacetate dihydrate (19513-05-4) → [Mn[benzil α-monoxime benzoylhydrazone](Cl)(H2O)](Cl)2

Guidance literature:

With KOH; In ethanol; N,N-dimethyl-formamide; byproducts: CH3COOH; to a hot soln. of the hydrazone-compd. in DMF-EtOH 1:4 (v/v) hot soln. of the Mn-compd. added in 1:1 molar ratio, stirred, 1 M KOH added to raise the pH to 8-10, gently warmed on a steam bath for ca.30 min; filtered, washed with distilled hot water, ethanol and diethyl ether, dried in vac., elem. anal.;

DOI:10.1081/SIM-200055249

upstream raw materials:

benzilmonoxime

benzoic acid hydrazide

(Z)-benzilmonooxime