Benzenethiol, 4-(1,1-dimethylethyl)-, gold(1+) salt

Base Information

• Chemical Name: Benzenethiol, 4-(1,1-dimethylethyl)-, gold(1+) salt
• CAS No.: 1197-00-8
• Molecular Formula: C10H14S.Au
• Molecular Weight: 362.246
• Mol file: 1197-00-8.mol

Synonyms:

Chemical Property of Benzenethiol, 4-(1,1-dimethylethyl)-, gold(1+) salt

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenethiol, 4-(1,1-dimethylethyl)-, gold(1+) salt

There total 2 articles about Benzenethiol, 4-(1,1-dimethylethyl)-, gold(1+) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogen tetrachloroaurate(III) tetrahydrate + 4-t-butylbenzenethiol (2396-68-1) → gold p-tert-butyl phenyl mercaptide (1197-00-8)

Guidance literature:

In ethanol; water; for 0.5h;

DOI:10.1002/anie.201907609

Reference yield:

→ gold p-tert-butyl phenyl mercaptide (1197-00-8)

Guidance literature:

Au (Au liquor), Et2S, p-tert-Butyl-thiophenol;

Reference yield: 52.0%

di-tert-butylphosphine (819-19-2) + gold p-tert-butyl phenyl mercaptide (1197-00-8) → Au(S(p-(t-Bu)C6H4))(PH(t-Bu)2) (643738-52-7)

Guidance literature:

In toluene; under N2; ligand (1 equiv.) in toluene added to soln. of Au complex in toluene; filtered through Celite; solvent evapd. from filtrate; washed with hexane; dried; elem. anal.;

DOI:10.1021/ic035006e

upstream raw materials:

4-t-butylbenzenethiol

Downstream raw materials:

gold

Au(S(p-(t-Bu)C₆H₄))(PH(t-Bu)2)

[Au(SC₆H₄Bu(t)-p)(PMe₂Ph)]