S-Deuteriated 2,4,6-triisopropylbenzenethiol

Base Information

• Chemical Name: S-Deuteriated 2,4,6-triisopropylbenzenethiol
• CAS No.: 160788-43-2
• Molecular Formula: C₁₅H₂₄S
• Molecular Weight: 237.414
• Mol file: 160788-43-2.mol

Synonyms:

Chemical Property of S-Deuteriated 2,4,6-triisopropylbenzenethiol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of S-Deuteriated 2,4,6-triisopropylbenzenethiol

There total 1 articles about S-Deuteriated 2,4,6-triisopropylbenzenethiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

2,4,6-Triisopropylthiophenol (22693-41-0) → S-Deuteriated 2,4,6-triisopropylbenzenethiol (160788-43-2)

Guidance literature:

With diclazuril; water-d2; sodium hydride; In tetrahydrofuran;

Reference yield: 50.0%

MoH4(P(C6H5)2CH2CH3)4 (32109-08-3) + S-Deuteriated 2,4,6-triisopropylbenzenethiol (160788-43-2) → deuterido(ethyldiphenylphosphine)(pyridine)tris(2,4,6-triisopropylbenzenethiolato)molybdenum(IV)

Guidance literature:

With pyridine; In not given; N2-atmosphere; addn. of excess of pyridine to Mo-complex soln., stirring (0°C, 1 h); pptn. on cold MeOH addn.; elem. anal.;

Reference yield:

WBr2(NNH2)(P(CH3)2C6H5)3 + S-Deuteriated 2,4,6-triisopropylbenzenethiol (160788-43-2) → W(2)H(2,4,6-triisopropylthiophenolate)3(PMe2Ph)2

Guidance literature:

With (C₂H₅)3N; In deuteromethanol; 3 equiv. of each, DSC6H2(i-Pr)3-2,4,6 and (C2H5)3N, were added to a suspension of the bromo-complex in MeOH and the mixt. stirred under N2 for 16 h;; the ppt. was washed with MeOD and dried in vac.;;

DOI:10.1039/DT9910001813

upstream raw materials:

2,4,6-Triisopropylthiophenol