[cis-(1,1-bis(diphenylphosphino)ferrocene)Pt(4-ethynylpyridyl)2]

Base Information

Chemical Name:[cis-(1,1-bis(diphenylphosphino)ferrocene)Pt(4-ethynylpyridyl)2]
CAS No.:405107-69-9
Molecular Formula:C₄₈H₃₆FeN₂P₂Pt
Molecular Weight:953.702
Hs Code.:

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Chemical Property of [cis-(1,1-bis(diphenylphosphino)ferrocene)Pt(4-ethynylpyridyl)2]

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Technology Process of [cis-(1,1-bis(diphenylphosphino)ferrocene)Pt(4-ethynylpyridyl)2]

There total 1 articles about [cis-(1,1-bis(diphenylphosphino)ferrocene)Pt(4-ethynylpyridyl)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 104413-90-3
[1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride

: 214548-37-5
4-ethynylpyridinelithium

: 405107-69-9
[cis-(1,1-bis(diphenylphosphino)ferrocene)Pt(4-ethynylpyridyl)2]

Guidance literature:: In tetrahydrofuran; byproducts: LiCl; a soln. of complex in THF was added to a soln. of Li-salt in THF at -70°C, the mixt. was allowed to warm to room temp., stirred for 16 h (N2); solvent was removed in vac., the residue was extd. with CH2Cl2, reduced in vol., diethyl ether was added, ppt. was dried in vac.; elem. anal.;
DOI:10.1021/om0109096

Reference yield: 81.0%

: 14220-21-4
rhenium(I) pentacarbonyl bromide

: 405107-69-9
[cis-(1,1-bis(diphenylphosphino)ferrocene)Pt(4-ethynylpyridyl)2]

: cyclobis([cis-(1,1-bis(diphenylphosphino)ferrocene)Pt(4-ethynylpyridyl)2](fac-Re(CO)3Br))

Guidance literature:: In tetrahydrofuran; a mixt. in THF was refluxed for 40 h (N2); hexane was added, ppt. was washed with cold ether, dried in vac., recrystd. from CH2Cl2-hexane; elem. anal.;
DOI:10.1021/om0109096