PtCl₂[1,1'-bis(diphenylphosphino)ferrocene]

Base Information

• Chemical Name: PtCl₂[1,1'-bis(diphenylphosphino)ferrocene]
• CAS No.: 104413-90-3
• Molecular Formula: C₃₄H₂₈Cl₂FeP₂Pt
• Molecular Weight: 820.377
• Mol file: 104413-90-3.mol

Synonyms:PtCl₂[1,1'-bis(diphenylphosphino)ferrocene]

Chemical Property of PtCl₂[1,1'-bis(diphenylphosphino)ferrocene]

Chemical Property:

Purity/Quality:

95%+ ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PtCl₂[1,1'-bis(diphenylphosphino)ferrocene]

There total 11 articles about PtCl₂[1,1'-bis(diphenylphosphino)ferrocene] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + potassium tetrachloroplatinate(II) (10025-99-7) → [1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride (104413-90-3)

Guidance literature:

In ethanol; water; benzene; from air and light protection; H2O (min.) added to a suspn. of Pt comp. (ethanol), a soln. (benzene) of dppf added dropwise, stirred for 12 h; ppt. filtered, washed (H2O, CH3OH), recrystd. (CH2Cl2-CH3OH); elem. anal.;

DOI:10.1016/S0277-5387(01)00783-5

Reference yield: 93.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + platinum(II) chloride (10025-65-7) → PtCl2[1,1'-bis(diphenylphosphino)ferrocene] (104413-90-3)

Guidance literature:

In benzene; suspending PtCl2 in benzene soln. of Fe(C5H4P(C6H5)2)2; refluxing for 20 h; filtn., crystn. on addn. of ethanol;

DOI:10.1016/S0020-1693(00)87684-7

Reference yield: 90.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + dichlorobis(dimethyl sulfoxide)platinum(II) → [1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride (104413-90-3)

Guidance literature:

In chloroform; Pt- and Fe-complexes in CHCl3 were heated gently for ca. 30 min with stirring; vol. was reduced, ether was added, filtered, washed with ether, dried invac. at 80°C for several h;

DOI:10.1016/S0022-328X(03)00397-8

upstream raw materials:

1,1'-bis-(diphenylphosphino)ferrocene

platinum(II) chloride

dichloro(1,5-cyclooctadiene)platinum(ll)

potassium tetrachloroplatinate(II)

Downstream raw materials:

bis(μ-chloro)bis(1,1'-bis(diphenylphosphino)ferrocene)diplatinum(II) tetrafluoroborate

{(1,1'-bis(diphenylphosphino)ferrocene)Pt(DMF)2}{BF₄}2

bis(μ-hydroxy)bis(1,1'-bis(diphenylphosphino)ferrocene)diplatinum(II) tetrafluoroborate

(1,1'-bis(diphenylphosphino)ferrocene)bis(pyrazol-1-yl)platinum(II)