meso-[ansa-Me₂Si-(2-Me-4-p-tolylcyclopenta[b]indol-3-yl)2ZrCl₂]

Base Information

Chemical Name:meso-[ansa-Me₂Si-(2-Me-4-p-tolylcyclopenta[b]indol-3-yl)2ZrCl₂]
CAS No.:1370658-89-1
Molecular Formula:C₄₀H₃₆Cl₂N₂SiZr
Molecular Weight:734.955
Hs Code.:

meso-[ansa-Me<sub>2</sub>Si-(2-Me-4-p-tolylcyclopenta[b]indol-3-yl)2ZrCl<sub>2</sub>]

Synonyms:

Suppliers and Price of meso-[ansa-Me₂Si-(2-Me-4-p-tolylcyclopenta[b]indol-3-yl)2ZrCl₂]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of meso-[ansa-Me₂Si-(2-Me-4-p-tolylcyclopenta[b]indol-3-yl)2ZrCl₂]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of meso-[ansa-Me₂Si-(2-Me-4-p-tolylcyclopenta[b]indol-3-yl)2ZrCl₂]

There total 2 articles about meso-[ansa-Me₂Si-(2-Me-4-p-tolylcyclopenta[b]indol-3-yl)2ZrCl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 1370658-88-0
2-methyl-4-para-tolyl-1,4-dihydrocyclopenta[b]indole

: 10026-11-6
zirconium(IV) chloride

: 75-78-5,30107-43-8
dimethylsilicon dichloride

: 1370658-89-1
ansa-Me₂Si-(2-Me-4-p-tolylcyclopenta[b]indol-3-yl)2ZrCl₂

Guidance literature:: With C₄H₉Li; In tetrahydrofuran; hexane; toluene; byproducts: LiCl; under dry Ar atm.; indole dissolved in toluene/THF; cooled to -80°C; BuLi in hexane added; Me2SiCl2 added; mixt. stirred at room temp. (24 h); decanted; concd. (vac.); dissolved (toluene); cooled to -80°C; BuLi added; heated to room temp.; solvent removed; recrystd. (Et2O);
DOI:10.1134/S0036023612010068

Reference yield: 26.0%

: 1370658-88-0
2-methyl-4-para-tolyl-1,4-dihydrocyclopenta[b]indole

: 10026-11-6
zirconium(IV) chloride

: 75-78-5,30107-43-8
dimethylsilicon dichloride

: 1370658-89-1
meso-[ansa-Me₂Si-(2-Me-4-p-tolylcyclopenta[b]indol-3-yl)2ZrCl₂]

: rac-[ansa-Me₂Si-(2-Me-4-p-tolylcyclopenta[b]indol-3-yl)2ZrCl₂]

Guidance literature:: With C₄H₉Li; In tetrahydrofuran; hexane; toluene; byproducts: LiCl; under dry Ar atm.; indole dissolved in toluene/THF; cooled to -80°C; BuLi in hexane added; Me2SiCl2 added; mixt. stirred at room temp. (24 h); decanted; concd. (vac.); dissolved (toluene); cooled to -80°C; BuLi added; heated to room temp.; solvent removed; recrystd. (Et2O); after fractionation of crystals in ether/hexane soln. rac and meso forms were obtained; elem. anal.;
DOI:10.1134/S0036023612010068