trans-carbonylchlorobis(triphenylarsine)iridium(I)

Base Information

• Chemical Name: trans-carbonylchlorobis(triphenylarsine)iridium(I)
• CAS No.: 15682-62-9
• Molecular Formula: C₃₇H₃₀As₂ClIrO
• Molecular Weight: 868.161
• Mol file: 15682-62-9.mol

Synonyms:

Chemical Property of trans-carbonylchlorobis(triphenylarsine)iridium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-carbonylchlorobis(triphenylarsine)iridium(I)

There total 3 articles about trans-carbonylchlorobis(triphenylarsine)iridium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

(tetrabutylammonium)[IrCl2(CO)2] (73191-02-3) + triphenyl-arsane (603-32-7) → trans-carbonylchlorobis(triphenylarsine)iridium(I) (15682-62-9,23954-42-9)

Guidance literature:

In tetrahydrofuran; CO-atmosphere; addn. of soln. of 2 equivs. of ligand to soln. of Ir-complex, stirring for 1 h at room temp.; evapn., addn. of EtOH, pptn. on concn.; NMR spectroscopy;

DOI:10.1016/S0277-5387(99)00225-9

Reference yield:

iridium(III) chloride trihydrate + triphenyl-arsane (603-32-7) → trans-carbonylchlorobis(triphenylarsine)iridium(I) (15682-62-9,23954-42-9)

Guidance literature:

With carbon monoxide; triethylamine; In dichloromethane; 2-methoxy-ethanol; refluxing soln. of complex and LiCl in CH3OC2H4OH purged with Ar for 15min, treated with CO for 3 h, cooled, (C2H5)3N and As(C6H5)3 soln. in CH2Cl2 added, refluxed for 10 min; cooled, filtered;

Reference yield:

sodium hexachloroiridate(IV) hexahydrate + triphenyl-arsane (603-32-7) + carbon monoxide (201230-82-2) → (Ir(As(C6H5)3)2(CO)Cl) (23954-42-9,15682-62-9)

Guidance literature:

In 2-methoxy-ethanol; CO was bubbled through 2-methoxyethanol soln. Na2IrCl6*6H2O for 3.5 h, AsPh3 was added to react. mixt. at room temp. and refluxed for 15 min; soln. was filtered hot and cooled;

DOI:10.1039/b107444j

upstream raw materials:

triphenyl-arsane

carbon monoxide

(tetrabutylammonium)[IrCl₂(CO)2]

Downstream raw materials:

(IrH₂(As(C₆H₅)3)2(CO)Cl)

IrCl(CO)[As(C₆H₅)3]2H₂

IrH((C₆H₅)2PC₆H₄CO)Cl(CO)(As(C₆H₅)3)

chlorobis(3-chlorobenzoato)bis(triphenylarsine)iridium(III)