trans-carbonylchlorobis(triphenylarsine)iridium(I)

Base Information

Chemical Name:trans-carbonylchlorobis(triphenylarsine)iridium(I)
CAS No.:15682-62-9
Molecular Formula:C₃₇H₃₀As₂ClIrO
Molecular Weight:868.161
Hs Code.:

Synonyms:

Suppliers and Price of trans-carbonylchlorobis(triphenylarsine)iridium(I)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trans-carbonylchlorobis(triphenylarsine)iridium(I)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trans-carbonylchlorobis(triphenylarsine)iridium(I)

There total 3 articles about trans-carbonylchlorobis(triphenylarsine)iridium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 73191-02-3
(tetrabutylammonium)[IrCl₂(CO)2]

: 603-32-7
triphenyl-arsane

: 15682-62-9,23954-42-9
trans-carbonylchlorobis(triphenylarsine)iridium(I)

Guidance literature:: In tetrahydrofuran; CO-atmosphere; addn. of soln. of 2 equivs. of ligand to soln. of Ir-complex, stirring for 1 h at room temp.; evapn., addn. of EtOH, pptn. on concn.; NMR spectroscopy;
DOI:10.1016/S0277-5387(99)00225-9

Reference yield:

: iridium(III) chloride trihydrate

: 603-32-7
triphenyl-arsane

: 15682-62-9,23954-42-9
trans-carbonylchlorobis(triphenylarsine)iridium(I)

Guidance literature:: With carbon monoxide; triethylamine; In dichloromethane; 2-methoxy-ethanol; refluxing soln. of complex and LiCl in CH3OC2H4OH purged with Ar for 15min, treated with CO for 3 h, cooled, (C2H5)3N and As(C6H5)3 soln. in CH2Cl2 added, refluxed for 10 min; cooled, filtered;

Reference yield:

: sodium hexachloroiridate(IV) hexahydrate

: 603-32-7
triphenyl-arsane

: 201230-82-2
carbon monoxide

: 23954-42-9,15682-62-9
(Ir(As(C₆H₅)3)2(CO)Cl)

Guidance literature:: In 2-methoxy-ethanol; CO was bubbled through 2-methoxyethanol soln. Na2IrCl6*6H2O for 3.5 h, AsPh3 was added to react. mixt. at room temp. and refluxed for 15 min; soln. was filtered hot and cooled;
DOI:10.1039/b107444j