Technology Process of [Pb(μ-Br)(C6H3-2,6-(2,6-C6H3-(i-Pr)2)2)]2
There total 1 articles about [Pb(μ-Br)(C6H3-2,6-(2,6-C6H3-(i-Pr)2)2)]2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
diethyl ether;
(Ar); Schlenk technique; soln. of Li compd. in Et2O was added dropwise over 40 min to suspn. of PbBr2 in Et2O with cooling in ice bath; soln. was warmed to room temp. and stirred overnight; Et2O removed (vac.); extd. (toluene); filtered through Celite; filtrate concd.; stored at -20°C; elem. anal.;
DOI:10.1021/ic049174y
- Guidance literature:
-
In
tetrahydrofuran;
(Ar); Schlenk technique; soln. of t-BuC6H4MgBr (1 equiv.) in THF was added to stirred soln. of Pb compd. in THF at 0°C; warmed to room temp. and stirred overnight; THF removed (vac.); extd. (toluene); filtered through Celite; concd.; kept at -20°C;
DOI:10.1021/ic049174y
- Guidance literature:
-
In
diethyl ether;
(Ar); Schlenk technique; soln. of CH3MgBr (1 equiv.) in Et2O was added via syringe to soln. of Pb compd. in Et2O at -30°C; warmed to roomtemp. and stirred for 3 h; Et2O removed (vac.); extd. (hexane); filtered through Celite; filtrate kept at -20°C for 2 d; elem. anal.;
DOI:10.1021/ic049174y
