WCl(CO)2(NO)(P(C₆H₅)3)2

Base Information

• Chemical Name: WCl(CO)2(NO)(P(C₆H₅)3)2
• CAS No.: 42536-20-9
• Molecular Formula: C₃₈H₃₀ClNO₃P₂W
• Molecular Weight: 829.912
• Mol file: 42536-20-9.mol

Synonyms:

Chemical Property of WCl(CO)2(NO)(P(C₆H₅)3)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of WCl(CO)2(NO)(P(C₆H₅)3)2

There total 4 articles about WCl(CO)2(NO)(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

W(OClO3)(CO)2(NO)(P(C6H5)3)2 (108215-12-9) → WCl(CO)2(NO)(P(C6H5)3)2 (42536-20-9,42536-21-0,84107-83-5)

Guidance literature:

With lithium chloride; In methanol; acetone; under N2, complex suspended in acetone, addn. of methanolic soln. of LiCl; crystn. within 10 min, elem. anal.;

Reference yield: 70.0%

[W(CO)3(NO)(P(C6H5)3)2](1+)*PF6(1-)=[W(CO)3(NO)(P(C6H5)3)2]PF6 (108234-41-9) → WCl(CO)2(NO)(P(C6H5)3)2 (42536-20-9,42536-21-0,84107-83-5)

Guidance literature:

With chloride; In dichloromethane; byproducts: CO; under N2, addn. of complex and Cl(1-) to CH2Cl2, homogeneous soln. within 1 min; evapn. of solvent at room temp., addn. of n-pentane, stirred and refluxed for 20-30min until pentane soln. nearly colorless, solid isolated, recrystn. from CH2Cl2 by addn. of EtOH;

Reference yield: 6.0%

W(OClO3)(CO)2(NO)(P(C6H5)3)2 (108215-12-9) → W(O2ClO2)(CO)(NO)(P(C6H5)3)2 + WCl(CO)2(NO)(P(C6H5)3)2 (42536-20-9,42536-21-0,84107-83-5)

Guidance literature:

In acetone; thermolysis in refluxing acetone;

upstream raw materials:

[W(CO)3(NO)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[W(CO)3(NO)(P(C₆H₅)3)2]PF₆

W(OClO₃)(CO)2(NO)(P(C₆H₅)3)2

W(CH₃)(CO)2(NO)(P(C₆H₅)3)2

hydrogen chloride

Downstream raw materials:

W(CH₃)(CO)2(NO)(P(C₆H₅)3)2

methylzinc chloride

W(⁽¹³⁾CH₃)(CO)2(NO)(P(C₆H₅)3)2