(4-t-BuC₆H₄NCH₂CH₂)3NMo-⁽¹⁵⁾N=⁽¹⁵⁾N-Me

Base Information

• Chemical Name: (4-t-BuC₆H₄NCH₂CH₂)3NMo-⁽¹⁵⁾N=⁽¹⁵⁾N-Me
• CAS No.: 351025-66-6
• Molecular Formula: C₃₇H₅₄MoN₆
• Molecular Weight: 680.803
• Mol file: 351025-66-6.mol

Synonyms:

Chemical Property of (4-t-BuC₆H₄NCH₂CH₂)3NMo-⁽¹⁵⁾N=⁽¹⁵⁾N-Me

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4-t-BuC₆H₄NCH₂CH₂)3NMo-⁽¹⁵⁾N=⁽¹⁵⁾N-Me

There total 1 articles about (4-t-BuC₆H₄NCH₂CH₂)3NMo-⁽¹⁵⁾N=⁽¹⁵⁾N-Me which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

Na(((4-t-BuC6H4NCH2CH2)3N)Mo-(15)N=(15)N)2Na(THF)2 + methyl p-toluene sulfonate (80-48-8) → (4-t-BuC6H4NCH2CH2)3NMo-(15)N=(15)N-Me (351025-66-6)

Guidance literature:

In tetrahydrofuran; under N2 atm. methyl tosylate was added to soln. Na((ArN3N)Mo-(15)N=(15)N)2Na)(THF)2 in THF and stirred at room temp. for 3 h; THF was removed, residue was dissolved in toluene, pentane was added, crystals were washed with pentane and dried in vacuo; elem. anal.;

DOI:10.1021/ic001123n

Reference yield: 100.0%

(4-t-BuC6H4NCH2CH2)3NMo-(15)N=(15)N-Me (351025-66-6) + methyl trifluoromethanesulfonate (333-27-7) → (((4-t-BuC6H4NCH2CH2)3N)Mo=(15)N-(15)NMe2)OTf (351025-84-8)

Guidance literature:

In toluene; under N2 atm. soln. methyl triflate in toluene was added at -35°Cto soln. ((4-t-BuC6H4NCH2CH2)3N)Mo(15)N(15)NMe in toluene and stirred f or 10 h;

DOI:10.1021/ic001123n

Reference yield: 95.0%

(4-t-BuC6H4NCH2CH2)3NMo-(15)N=(15)N-Me (351025-66-6) + methyl trifluoromethanesulfonate (333-27-7) → (((4-t-BuC6H4NCH2CH2)3N)Mo=N-NMe2)OTf (351025-78-0)

Guidance literature:

In toluene; under N2 atm. soln. methyl triflate in toluene was added at -35°Cto soln. ((ArNCH2CH2)3N)MoNNMe in toluene and stirred for 10 h; soln. was concd., pentane was added, crystals were colected, washed withEt2O, and dried in vacuo; elem. anal.;

DOI:10.1021/ic001123n

upstream raw materials:

methyl p-toluene sulfonate

Downstream raw materials:

(((4-t-BuC₆H₄NCH₂CH₂)3N)Mo=N-N(⁽¹³⁾CH₃)(CH₃))OTf

(((4-t-BuC₆H₄NCH₂CH₂)3N)Mo=N-NMe₂)OTf

(((4-t-BuC₆H₄NCH₂CH₂)3N)Mo=⁽¹⁵⁾N-⁽¹⁵⁾NMe₂)OTf