trans-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex)

Base Information

• Chemical Name: trans-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex)
• CAS No.: 1209494-94-9
• Molecular Formula: C₁₃H₁₅Cl₂NOPtS
• Molecular Weight: 499.32
• Mol file: 1209494-94-9.mol

Synonyms:

Chemical Property of trans-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex)

There total 12 articles about trans-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.4%

potassium trichloroplatinite(II) (14099-24-2) + Methyl p-tolyl sulfoxide (934-72-5) → cis-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex) (183293-92-7,183506-91-4,1209494-94-9)

Guidance literature:

In water; 1 equiv. of sulfoxide was added under stirring, soln., was kept at room temp. for 24 h; ppt. was filtered off, dried in a thermostat at 50 °C;

DOI:10.1023/A:1011357929566

Reference yield: 90.4%

potassium trichloroplatinite(II) (14099-24-2) + (R)-(+)-methyl p-tolyl sulfoxide (1519-39-7) → cis-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex) (183293-92-7,183506-91-4,1209494-94-9)

Guidance literature:

In water; 79.6 mg of potassium (-)trichloropyridineplatinite(II) dissolved in 4 mlof water in a beaker; 29.3 mg of (+)methyl-para-tolylsulfoxide slowly a dded with stirring; kept at room temp. for 1 d; white flocculant ppt. formed; filtration; drying in thermostate at 50°C; isolation of (-)-isomer;

DOI:10.1023/A:1013096802361

Reference yield: 88.6%

pyridine (110-86-1) + potassium (-)-trichloro[S-methyl p-tolyl sulfoxide]platinate(II) (198292-42-1,127157-15-7) → trans-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex) (183293-92-7,183506-91-4,1209494-94-9)

Guidance literature:

In water; 1 equiv. of C5H5N in a 0.163 M aq. soln. was added to aq. soln. of Pt-complex under stirring at 15 °C, stirring for 20 min; ppt. was filtered off, dried in a thermostat at 50 °C;

DOI:10.1023/A:1011357929566

upstream raw materials:

potassium trichloroplatinite(II)

Methyl p-tolyl sulfoxide

(R)-(+)-methyl p-tolyl sulfoxide

trans-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex)

Downstream raw materials:

trans-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex)

cis-[Pt(C₅H₅N)(Ph₃PS)Cl₂]

trans-[Pt(C₅H₅N)(Ph₃PS)Cl₂]

cis-[PtCl₂(C₅H₅N)(Me₂SO)]