C₃₆H₃₆F₃N₃O₁₄

Base Information

• Chemical Name: C₃₆H₃₆F₃N₃O₁₄
• CAS No.: 180182-57-4
• Molecular Formula: C₃₆H₃₆F₃N₃O₁₄
• Molecular Weight: 791.689
• Mol file: 180182-57-4.mol

Synonyms:

Chemical Property of C₃₆H₃₆F₃N₃O₁₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₆H₃₆F₃N₃O₁₄

There total 7 articles about C₃₆H₃₆F₃N₃O₁₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-Nitro-benzoic acid (2S,3S,4S)-2-methyl-6-phenylsulfanyl-4-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-3-yl ester (179992-19-9) + p-Methoxybenzyl 3-O-p-nitrobenzoyl-2-deoxyfucoside (179992-18-8) → C36H36F3N3O14 (180182-57-4)

Guidance literature:

With iodonium di(2,4,6-trimethylpyridine) perchlorate; 4 A molecular sieve; In diethyl ether; 1,2-dichloro-ethane; at 5 - 10 ℃; for 2h;

DOI:10.1039/P19960001327

Reference yield:

2,3,6-trideoxy-1,4-di-O-p-nitrobenzoyl-3-trifluoroacetamido-L-lyxopyranose (52583-22-9) → C36H36F3N3O14 (180182-57-4)

Guidance literature:

Multi-step reaction with 2 steps

1: TMSOTf / CH₂Cl₂ / 12 h / Ambient temperature

2: 4 Angstroem molecular sieves, iodonium dicollidine perchlorate / 1,2-dichloro-ethane; diethyl ether / 2 h / 5 - 10 °C

With trimethylsilyl trifluoromethanesulfonate; iodonium di(2,4,6-trimethylpyridine) perchlorate; 4 A molecular sieve; In diethyl ether; dichloromethane; 1,2-dichloro-ethane;

DOI:10.1039/P19960001327

Reference yield:

4-nitro-benzoyl chloride (122-04-3) → C36H36F3N3O14 (180182-57-4)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine / CH₂Cl₂ / 1 h / -15 °C

2: 4 Angstroem molecular sieves, iodonium dicollidine perchlorate / 1,2-dichloro-ethane; diethyl ether / 2 h / 5 - 10 °C

With pyridine; iodonium di(2,4,6-trimethylpyridine) perchlorate; 4 A molecular sieve; In diethyl ether; dichloromethane; 1,2-dichloro-ethane;

DOI:10.1039/P19960001327

upstream raw materials:

4-Nitro-benzoic acid (2S,3S,4S)-2-methyl-6-phenylsulfanyl-4-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-3-yl ester

p-Methoxybenzyl 3-O-p-nitrobenzoyl-2-deoxyfucoside

2,3,6-trideoxy-1,4-di-O-p-nitrobenzoyl-3-trifluoroacetamido-L-lyxopyranose

4-nitro-benzoyl chloride

Downstream raw materials:

C₄₉H₄₄F₃N₃O₂₀

C₄₈H₄₂F₃N₃O₁₉

p-Nitrobenzoyl 3-O-p-nitrobenzoyl-4-O-(3-N-trifluoroacetyl-4-O-p-nitrobenzoyl-α-L-daunosaminyl)-2-deoxy-L-fucoside