(1aα,4aα)-decahydro-4a-methyl-2-(phenylseleno)cyclopropanaphthalene

Base Information

Chemical Name:(1aα,4aα)-decahydro-4a-methyl-2-(phenylseleno)cyclopropanaphthalene
CAS No.:123827-02-1
Molecular Formula:C₁₈H₂₄Se
Molecular Weight:319.349
Hs Code.:

(1aα,4aα)-decahydro-4a-methyl-2-(phenylseleno)cyclopropa<d>naphthalene

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1aα,4aα)-decahydro-4a-methyl-2-(phenylseleno)cyclopropanaphthalene

Chemical Property:

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Technology Process of (1aα,4aα)-decahydro-4a-methyl-2-(phenylseleno)cyclopropanaphthalene

There total 5 articles about (1aα,4aα)-decahydro-4a-methyl-2-(phenylseleno)cyclopropanaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 2179-79-5
phenyl selenocyanate

: 13421-36-8,13903-60-1,40447-85-6,134003-39-7,134003-42-2
(1aα,2β,4aβ)-decahydro-4a-methylcyclopropanaphthalen-2-ol

: 123827-02-1,134003-40-0,134003-41-1,134003-43-3,134003-44-4
(1aα,4aβ)-decahydro-4a-methyl-2-(phenylseleno)cyclopropanaphthalene

Guidance literature:: With tributylphosphine; In tetrahydrofuran; for 16h; from -78 degC to room t.;
DOI:10.1039/c39890000332

Reference yield: 72.0%

: 2179-79-5
phenyl selenocyanate

: 13421-36-8,13903-60-1,40447-85-6,134003-39-7,134003-42-2
(1aβ,2α,4aβ)-decahydro-4a-methylcyclopropanaphthalen-2-ol

: 123827-02-1,134003-40-0,134003-41-1,134003-43-3,134003-44-4
(1aα,4aα)-decahydro-4a-methyl-2-(phenylseleno)cyclopropanaphthalene

Guidance literature:: With tributylphosphine; In tetrahydrofuran; -78 deg C up to room temp.;
DOI:10.1021/jo00012a009

Reference yield:

: 31654-83-8,40447-83-4,83606-04-6,83606-05-7,83648-94-6,26675-10-5
(+/-)-cis-4a-methyl-2,3,4,4a,5,6,7,8-octahydronaphthalen-2-ol

: 123827-02-1,134003-40-0,134003-41-1,134003-43-3,134003-44-4
(1aα,4aβ)-decahydro-4a-methyl-2-(phenylseleno)cyclopropanaphthalene

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / Zn(Cu) / diethyl ether / 16 h / Heating

2: 85 percent / Bu₃P / tetrahydrofuran / 16 h / from -78 degC to room t.

With zinc copper; tributylphosphine; In tetrahydrofuran; diethyl ether;
DOI:10.1039/c39890000332