{PPN}{Fe₂Co(CO)7(bis(dimethylphosphino)methane)(CCO)*CH₂Cl₂

Base Information

• Chemical Name: {PPN}{Fe₂Co(CO)7(bis(dimethylphosphino)methane)(CCO)*CH₂Cl₂
• CAS No.: 119239-74-6
• Molecular Formula: CH₂Cl₂*C₁₄H₁₄CoFe₂O₈P₂*C₃₆H₃₀NP₂
• Molecular Weight: 1166.42
• Mol file: 119239-74-6.mol

Synonyms:

Chemical Property of {PPN}{Fe₂Co(CO)7(bis(dimethylphosphino)methane)(CCO)*CH₂Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {PPN}{Fe₂Co(CO)7(bis(dimethylphosphino)methane)(CCO)*CH₂Cl₂

There total 1 articles about {PPN}{Fe₂Co(CO)7(bis(dimethylphosphino)methane)(CCO)*CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

{bis(triphenylphosphine)nitrogen}{Fe2Co(CO)9(CCO)} (88657-64-1) + dmpm (64065-08-3) → {PPN}{Fe2Co(CO)7(bis(dimethylphosphino)methane)(CCO)*CH2Cl2 (119239-74-6)

Guidance literature:

In dichloromethane; soln. of complex treated with dmpm (N2), stirred (4 h, soln. became red-brown); solvent removed (vac.), oil dissolved in CH2Cl2, filtered, Et2O added, agitated, cooled (0°C overnight, -78°C for 2 h), filtered, product washed with MeOH and EtOH, dried (vac.); elem. anal.;

Reference yield:

{PPN}{Fe2Co(CO)7(bis(dimethylphosphino)methane)(CCO)*CH2Cl2 (119239-74-6) + [13C]Carbon monoxide (1641-69-6) → {PPN}{Fe2Co((13)CO)7(bis(dimethylphosphino)methane)(C(13)CO) (119145-74-3)

Guidance literature:

In not given; carbonyl exchange (1 atm (13)CO, room temp., 24 h); (13)CO enrichment at all 8 CO-groups;

upstream raw materials:

{bis(triphenylphosphine)nitrogen}{Fe₂Co(CO)9(CCO)}

dmpm

Downstream raw materials:

{PPN}{Fe₂Co(⁽¹³⁾CO)7(bis(dimethylphosphino)methane)(C⁽¹³⁾CO)

Refernces