IrH₂Cl(CO)(9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene)

Base Information

• Chemical Name: IrH₂Cl(CO)(9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene)
• CAS No.: 910781-06-5
• Molecular Formula: C₄₀H₃₄ClIrO₂P₂
• Molecular Weight: 836.329
• Mol file: 910781-06-5.mol

Synonyms:

Chemical Property of IrH₂Cl(CO)(9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrH₂Cl(CO)(9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene)

There total 1 articles about IrH₂Cl(CO)(9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

parahydrogen (1333-74-0,12385-13-6) + IrCl(CO)2(9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene) (910781-05-4) → IrH2Cl(CO)(9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene) (910781-06-5,910999-52-9)

Guidance literature:

In toluene; (N2); Ir complex dissolved in toluene, degassed, pressurized with 2 atm of H2, heated at 70°C for 1.5 h; allowed to cool, decanted, dissolved in CH2Cl2, crystd. by layering withEt2O at ambient temp., washed (pentane), dried (vac.); elem. anal.;

DOI:10.1021/ic060731l

Reference yield:

IrH2Cl(CO)(9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene) (910781-06-5,910999-52-9) → IrH2Cl(CO)(9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene)

Guidance literature:

In not given; (N2) at 90°C for 1 d;

DOI:10.1021/ic060731l

upstream raw materials:

parahydrogen

IrCl(CO)2(9,9-dimethyl-4,6-bis(diphenylphosphino)xanthene)