Os3(1-η1-C(OEt)Ph)(1,2-μ-H;1,2-μ-O=C(Me))(CO)9

Base Information

• Chemical Name: Os3(1-η1-C(OEt)Ph)(1,2-μ-H;1,2-μ-O=C(Me))(CO)9
• CAS No.: 91312-97-9
• Molecular Formula: C₂₀H₁₄O₁₁Os₃
• Molecular Weight: 1000.92
• Mol file: 91312-97-9.mol

Synonyms:

Chemical Property of Os3(1-η1-C(OEt)Ph)(1,2-μ-H;1,2-μ-O=C(Me))(CO)9

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Os3(1-η1-C(OEt)Ph)(1,2-μ-H;1,2-μ-O=C(Me))(CO)9

There total 1 articles about Os3(1-η1-C(OEt)Ph)(1,2-μ-H;1,2-μ-O=C(Me))(CO)9 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

Os3[μ-H,μ-O=CMe](CO)10 (65908-54-5) + trifluoromethanesulfonic acid ethyl ester (425-75-2) + phenyllithium (591-51-5) + lithium bromide (7550-35-8) → Os3(1,2-μ-Br;1,2-μ-O=C(Me))(CO)10 (91312-91-3) + Os3(1-η1-C(OEt)Ph)(1,2-μ-H;1,2-μ-O=C(Me))(CO)9 (91312-97-9)

Guidance literature:

In diethyl ether; cyclohexane; under N2, soln. of Os complex in dry freshly distd. Et2O titrated at 0°C with PhLi (2.4 M in C6H12/Et2O), treated with 1.27 M EtOSO2CF3 in Et2O, stirred for 108 h; evapd., chromd. (SiO2, petroleum ether, CH2Cl2);

DOI:10.1021/ja00332a029

upstream raw materials:

Os3[μ-H,μ-O=CMe](CO)10

trifluoromethanesulfonic acid ethyl ester

phenyllithium

lithium bromide