(5,10,15,20-tetra-p-tolylporphyrinato)[(4-methoxyphenyl)ethyl]iridium(III)

Base Information

Chemical Name:(5,10,15,20-tetra-p-tolylporphyrinato)[(4-methoxyphenyl)ethyl]iridium(III)
CAS No.:872415-70-8
Molecular Formula:C₅₇H₄₇IrN₄O
Molecular Weight:996.246
Hs Code.:

Synonyms:

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Chemical Property of (5,10,15,20-tetra-p-tolylporphyrinato)[(4-methoxyphenyl)ethyl]iridium(III)

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Technology Process of (5,10,15,20-tetra-p-tolylporphyrinato)[(4-methoxyphenyl)ethyl]iridium(III)

There total 1 articles about (5,10,15,20-tetra-p-tolylporphyrinato)[(4-methoxyphenyl)ethyl]iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 872415-81-1
(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride

: 14425-64-0
4-methoxyphenethyl bromide

: 872415-70-8
(5,10,15,20-tetra-p-tolylporphyrinato)[(4-methoxyphenyl)ethyl]iridium(III)

Guidance literature:: With sodium hydroxide; sodium tetrahydroborate; In tetrahydrofuran; water; under N2 atm. to suspn. Ir complex in THF soln. NaBH4 in 1 M aq. NaOH was added and heated at 70°C for 2 h, cooled to room temp., MeOC6H4CH2CH2Br was added and heated at 70°C for 2 h; react. mixt. was extd. with CH2Cl2/H2O, org. layer was dried over MgSO4,filtered and evapd. in vacuo, column chromy. on silica (hexane-CH2Cl2 4 :1), recrystn. from CH2Cl2-MeOH; elem. anal.;
DOI:10.1021/om050661a

Reference yield: 73.0%

: 2564-83-2,45842-10-2,126517-51-9,25657-03-8,26933-82-4,54637-06-8,64104-42-3
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

: 872415-70-8
(5,10,15,20-tetra-p-tolylporphyrinato)[(4-methoxyphenyl)ethyl]iridium(III)

: 872415-76-4
(5,10,15,20-tetra-p-tolylporphyrinato)[2-(4-methoxyphenyl)-2-oxoethyl]iridium(III)

Guidance literature:: In benzene; Ir complex and 15 equiv. TEMPO in benzene was heated at 80°C in oil bath in Teflon- screw-capped tube for 12 days; react. mixt. was dried under high vac. and chromed. on silica column (hexane-CH2Cl2 4:1);
DOI:10.1021/om050661a