BenzenaMine, 2,2',2'',2'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-, stereoisoMer

Base Information

Chemical Name:BenzenaMine, 2,2',2'',2'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-, stereoisoMer
CAS No.:68070-27-9
Molecular Formula:C₄₄H₃₄N₈
Molecular Weight:674.808
Hs Code.:

Synonyms:

Suppliers and Price of BenzenaMine, 2,2',2'',2'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-, stereoisoMer

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 9 raw suppliers

Chemical Property of BenzenaMine, 2,2',2'',2'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-, stereoisoMer

Chemical Property:

Density:1.350±0.06 g/cm3(Predicted)

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

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Technology Process of BenzenaMine, 2,2',2'',2'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-, stereoisoMer

There total 2 articles about BenzenaMine, 2,2',2'',2'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-, stereoisoMer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 5,10,15,20-tetrakis(2-nitrophenyl)porphyrin

: 52199-35-6,68070-27-9,68070-28-0,68070-29-1,68070-30-4
cis-α,α,α,α-atropisomer 5,10,15,20-tetrakis(2-aminophenyl)porphyrin

Guidance literature:: 5,10,15,20-tetrakis(2-nitrophenyl)porphyrin; With hydrogenchloride; tin(II) chloride dihdyrate; In water; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique; Glovebox;

In water; at 65 ℃; for 0.416667h; Inert atmosphere; Schlenk technique; Glovebox;
DOI:10.1039/c5dt04563k

Reference yield:

: 109-97-7,30604-81-0
pyrrole

: 552-89-6
2-nitro-benzaldehyde

: 52199-35-6,68070-27-9,68070-28-0,68070-29-1,68070-30-4
(-)-meso-α,α,α,α-tetrakis(2-aminophenyl)porphyrin

Guidance literature:: Yield given. Multistep reaction;

Reference yield: 99.0%

: 13446-03-2
manganese(II) bromide

: ammonium chloride

: 52199-35-6,68070-27-9,68070-28-0,68070-29-1,68070-30-4
cis-α,α,α,α-atropisomer 5,10,15,20-tetrakis(2-aminophenyl)porphyrin

: 1384451-30-2,98767-27-2
tetrakis(2-aminophenyl)porphyrinatochloromanganese(III)

Guidance literature:: With 2,6-lutidine; In tetrahydrofuran; (Ar) free base porphyrin reacted with MnCl2 in THF in the presence of 2,6-lutidine for 36h at 23 °C, stirred in air, solvent removed in vac, redissolved in CH2Cl2, filtered, washed with aq. NH4Cl; dried over MgSO4, conc.;
DOI:10.1016/j.jcat.2012.04.016