tricyclohexylphosphine(1,5-hexadiene)nickel

Base Information

Chemical Name:tricyclohexylphosphine(1,5-hexadiene)nickel
CAS No.:74945-90-7
Molecular Formula:C₂₄H₄₃NiP
Molecular Weight:421.269
Hs Code.:

Synonyms:

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Chemical Property of tricyclohexylphosphine(1,5-hexadiene)nickel

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Technology Process of tricyclohexylphosphine(1,5-hexadiene)nickel

There total 2 articles about tricyclohexylphosphine(1,5-hexadiene)nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.3%

: bis(η3-allyl)nickel(II)

: 2622-14-2
tricyclohexylphosphine

: 74945-90-7
tricyclohexylphosphine(1,5-hexadiene)nickel

Guidance literature:: In diethyl ether; toluene; Ni complex in ether added to soln. of org. compd. in toluene at -78°C, mixture allowed to warm to -15°C, stirred for 2 d; filtration at -30°C, washing (ether), drying in vac.; elem. anal.;
DOI:10.1016/S0022-328X(00)81073-6

Reference yield: 64.0%

: 2622-05-1
allylmagnesium bromide

: 83864-14-6
nickel dichloride

: 2622-14-2
tricyclohexylphosphine

: 74945-90-7
tricyclohexylphosphine(1,5-hexadiene)nickel

Guidance literature:: In tetrahydrofuran; diethyl ether; at 50 ℃; for 4h; Schlenk technique; Glovebox; Inert atmosphere;
DOI:10.1021/jacs.6b11412

Reference yield:

: 74945-90-7
tricyclohexylphosphine(1,5-hexadiene)nickel

: 103-71-9
phenyl isocyanate

: 114572-12-2
Ni(P(C₆H₁₁)3)(N(C₆H₅)C(O)CH₂CH(CH₂)2CHCH₂)

: 114572-13-3
Ni(P(C₆H₁₁)3)(N(C₆H₅)C(O)CH((CH₂)2CHCH₂)CH₂)

Guidance literature:: In diethyl ether; to a suspn. of Ni-complex in diethyl ether phenylisocyanate is added at-78°C, mixt. is allowed to warm to -10°C with stirring (without air); after 2 days the solid is filtered off, washed with diethyl ether and dried; mixt of regioisomers, total yield 60%;
DOI:10.1016/0022-328X(87)80256-5