dichlorido(4,4'-diphenyl-2,2'-bipyridine)platinum(II)

Base Information

• Chemical Name: dichlorido(4,4'-diphenyl-2,2'-bipyridine)platinum(II)
• CAS No.: 126951-59-5
• Molecular Formula: C₂₂H₁₆Cl₂N₂Pt
• Molecular Weight: 574.368
• Mol file: 126951-59-5.mol

Synonyms:

Chemical Property of dichlorido(4,4'-diphenyl-2,2'-bipyridine)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichlorido(4,4'-diphenyl-2,2'-bipyridine)platinum(II)

There total 2 articles about dichlorido(4,4'-diphenyl-2,2'-bipyridine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

potassium tetrachloroplatinate(II) (10025-99-7) + 4,4'-diphenyl-2,2'-bipyridine (6153-92-0) → dichlorido(4,4'-diphenyl-2,2'-bipyridine)platinum(II) (126951-59-5)

Guidance literature:

In water; acetone; extn. of bipy derivative into Me2CO, filtration into Pt-complex (in H2O), stirring and gentle heating for 1 h (pptn.); collection (filtration), washing (H2O, EtOH), drying (vac., SiO2); elem.anal.;

DOI:10.1016/S0022-328X(96)06412-1

Reference yield:

potassium tetrachloroplatinate + 4,4'-diphenyl-2,2'-bipyridine (6153-92-0) → dichlorido(4,4'-diphenyl-2,2'-bipyridine)platinum(II) (126951-59-5)

Guidance literature:

DOI:10.1039/c4dt01929f

Reference yield: 45.0%

dichlorido(4,4'-diphenyl-2,2'-bipyridine)platinum(II) (126951-59-5) + 4-Ethynylbenzaldehyde (63697-96-1) → Pt(4,4'-diphenylbipyridine)(p-CCC6H4CHO)2 (560133-00-8)

Guidance literature:

copper(l) iodide; In dimethyl sulfoxide; triethylamine; under N2; Pt-contg. compd. (0.17 mmol), CuI, 4-ethynylbenzaldehyde (2.3 mmol) and DMSO:NEt3 (5:1 v/v) were placed into a Schlenk tube; the mixt.was stirred at 65°C for 20-24 h; the solvent was removed, H2O was added; vac. filtration; the complex wasdissolved in a min. amt. of CH2Cl2 and recrystd. from hexanes; preparat ive TLC on alumina (CH2Cl2/MeOH); elem. anal.;

DOI:10.1021/ic0263084

upstream raw materials:

potassium tetrachloroplatinate(II)

4,4'-diphenyl-2,2'-bipyridine

Downstream raw materials:

Pt(4,4'-diphenylbipyridine)(p-CCC₆H₄CHO)2

(4,4'-diphenyl-2,2'-bipyridine)(N-methyl-thioxothiazolin-4,5-dithiolate)platinum(II)