Stannane, trimethyl[[4-(trifluoromethyl)phenyl]ethynyl]-

Base Information

Chemical Name:Stannane, trimethyl[[4-(trifluoromethyl)phenyl]ethynyl]-
CAS No.:121721-20-8
Molecular Formula:C12H13F3Sn
Molecular Weight:332.94
Hs Code.:
Mol file:121721-20-8.mol

Synonyms:

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Chemical Property of Stannane, trimethyl[[4-(trifluoromethyl)phenyl]ethynyl]-

Chemical Property:

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Technology Process of Stannane, trimethyl[[4-(trifluoromethyl)phenyl]ethynyl]-

There total 1 articles about Stannane, trimethyl[[4-(trifluoromethyl)phenyl]ethynyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 705-31-7
4-trifluoromethylphenylacetylene

: 1066-45-1
trimethyltin(IV)chloride

: 121721-20-8
trimethyl(p-trifluoromethylphenylethynyl)stannane

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; Addn. of butyl-lithium in hexane to a soln. of the alkyne in anhyd. ether at -30°C, stirring for 15 min under dry N2, addn. of a soln. of the trialkylchlorostannane in ether, stirring for 30 min, rising temp. to room temp. during 1h.; Addn. of light petroleum, filtration under a stream of dry N2, evapn., distn. at reduced pressure, elem. anal.;

Reference yield:

: 121721-20-8
trimethyl(p-trifluoromethylphenylethynyl)stannane

: 165617-59-4
4,8-dibromo-1H,5H-benzo[1,2-c:4,5-c']bis([1,2,5] thiadiazole)

: C₂₄H₈F₆N₄S₂

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; at 100 ℃; for 3h; Inert atmosphere;

Reference yield:

: 673-32-5
1-Phenylprop-1-yne

: 121721-20-8
trimethyl(p-trifluoromethylphenylethynyl)stannane

: 1227476-15-4
Azobenzene

: C₂₄H₁₈F₃N

Guidance literature:: 1-Phenylprop-1-yne; trimethyl(p-trifluoromethylphenylethynyl)stannane; Azobenzene; With 2C₆H₅N^(2-)*2Ti⁽⁴⁺⁾*4Cl^(1-)*2C₅H₅N; In toluene; at 90 ℃; for 9h;

With hydrogenchloride; methanol; regioselective reaction;
DOI:10.1039/d0sc01576h