C₂₇H₄₆O₄Si

Base Information

• Chemical Name: C₂₇H₄₆O₄Si
• CAS No.: 1300655-90-6
• Molecular Formula: C₂₇H₄₆O₄Si
• Molecular Weight: 462.745
• Mol file: 1300655-90-6.mol

Synonyms:

Chemical Property of C₂₇H₄₆O₄Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₇H₄₆O₄Si

There total 5 articles about C₂₇H₄₆O₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C13H18O2 (1300655-86-0) → C27H46O4Si (1300655-90-6)

Guidance literature:

Multi-step reaction with 4 steps

1.1: n-butyllithium / hexane; tert-butyl methyl ether / 0.17 h / -78 °C / Inert atmosphere

1.2: 0.67 h / 0 - 20 °C / Inert atmosphere

2.1: sodium hydride / hexane / 2 h / Inert atmosphere; Reflux

3.1: acetylacetonatodicarbonylrhodium(l) / benzene / 4.5 h / 60 °C / 51716.2 Torr / Autoclave

3.2: 1 h / 40 °C / Inert atmosphere

4.1: 2,6-dimethylpyridine / dichloromethane / 1 h / -78 °C / Inert atmosphere

With 2,6-dimethylpyridine; acetylacetonatodicarbonylrhodium(l); n-butyllithium; sodium hydride; In hexane; dichloromethane; tert-butyl methyl ether; benzene;

DOI:10.1021/ja201467z

Reference yield:

C24H36O2Si (1300655-88-2) → C27H46O4Si (1300655-90-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: acetylacetonatodicarbonylrhodium(l) / benzene / 4.5 h / 60 °C / 51716.2 Torr / Autoclave

1.2: 1 h / 40 °C / Inert atmosphere

2.1: 2,6-dimethylpyridine / dichloromethane / 1 h / -78 °C / Inert atmosphere

With 2,6-dimethylpyridine; acetylacetonatodicarbonylrhodium(l); In dichloromethane; benzene;

DOI:10.1021/ja201467z

Reference yield:

(E)-hex-4-en-1-ol (928-92-7) → C27H46O4Si (1300655-90-6)

Guidance literature:

Multi-step reaction with 6 steps

1.1: sodium hydride / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere

1.2: 12 h / 0 - 70 °C / Inert atmosphere

2.1: Oxone; Shi's ketone; tetra(n-butyl)ammonium hydrogensulfate; edetate disodium; potassium carbonate; acetic acid; potassium hydroxide / Dimethoxymethane; acetonitrile / 3 h / -10 °C / Inert atmosphere; aq. buffer

3.1: n-butyllithium / hexane; tert-butyl methyl ether / 0.17 h / -78 °C / Inert atmosphere

3.2: 0.67 h / 0 - 20 °C / Inert atmosphere

4.1: sodium hydride / hexane / 2 h / Inert atmosphere; Reflux

5.1: acetylacetonatodicarbonylrhodium(l) / benzene / 4.5 h / 60 °C / 51716.2 Torr / Autoclave

5.2: 1 h / 40 °C / Inert atmosphere

6.1: 2,6-dimethylpyridine / dichloromethane / 1 h / -78 °C / Inert atmosphere

With 2,6-dimethylpyridine; Oxone; acetylacetonatodicarbonylrhodium(l); n-butyllithium; Shi's ketone; tetra(n-butyl)ammonium hydrogensulfate; edetate disodium; sodium hydride; potassium carbonate; acetic acid; potassium hydroxide; In tetrahydrofuran; Dimethoxymethane; hexane; dichloromethane; tert-butyl methyl ether; acetonitrile; benzene;

DOI:10.1021/ja201467z

upstream raw materials:

C₁₃H₁₈O₂

C₁₆H₂₂O₂

C₂₄H₃₆O₂Si

(E)-hex-4-en-1-ol

Downstream raw materials:

C₃₁H₅₂O₆Si

C₃₄H₅₆O₈Si

C₄₁H₆₇NO₇S₂Si

C₃₆H₆₀O₈Si